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A High-Efficiency Grid-Tie Battery Energy Storage SystemQian, Hao 25 October 2011 (has links)
Lithium-ion based battery energy storage system has become one of the most popular forms of energy storage system for its high charge and discharge efficiency and high energy density. This dissertation proposes a high-efficiency grid-tie lithium-ion battery based energy storage system, which consists of a LiFePO4 battery based energy storage and associated battery management system (BMS), a high-efficiency bidirectional ac-dc converter and the central control unit which controls the operation mode and grid interface of the energy storage system. The BMS estimates the state of charge (SOC) and state of health (SOH) of each battery cell in the pack and applies active charge equalization to balance the charge of all the cells in the pack. The bidirectional ac-dc converter works as the interface between the battery pack and the ac grid, which needs to meet the requirements of bidirectional power flow capability and to ensure high power factor and low THD as well as to regulate the dc side power regulation.
A highly efficient dual-buck converter based bidirectional ac-dc converter is proposed. The implemented converter efficiency peaks at 97.8% at 50-kHz switching frequency for both rectifier and inverter modes. To better utilize the dc bus voltage and eliminate the two dc bus bulk capacitors in the conventional dual-buck converter, a novel bidirectional ac-dc converter is proposed by replacing the capacitor leg of the dual-buck converter based single-phase bidirectional ac-dc converter with a half-bridge switch leg. Based on the single-phase bidirectional ac-dc converter topology, three novel three-phase bidirectional ac-dc converter topologies are proposed.
In order to control the bidirectional power flow and at the same time stabilize the system in mode transition, an admittance compensator along with a quasi-proportional-resonant (QPR) controller is adopted to allow smooth startup and elimination of the steady-state error over the entire load range. The proposed QPR controller is designed and implemented with a digital controller. The entire system has been simulated in both PSIM and Simulink and verified with hardware experiments. Small transient currents are observed with the power transferred from rectifier mode to inverter mode at peak current point and also from inverter mode to rectifier mode at peak current point.
The designed BMS monitors and reports all battery cells parameters in the pack and estimates the SOC of each battery cell by using the Coulomb counting plus an accurate open-circuit voltage model. The SOC information is then used to control the isolated bidirectional dc-dc converter based active cell balancing circuits to mitigate the mismatch among the series connected cells. Using the proposed SOC balancing technique, the entire battery storage system has demonstrated more capacity than the system without SOC balancing. / Ph. D.
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A model for material handling improvements when using automated storage systems: A case study / En modell för förbättringar av materialhantering genom användandet av automatiserade lagersystem: En fallstudieThongmal Larsson, Marie January 2010 (has links)
<p>The purpose of this thesis is to create a model of how to organize the placements of articles in an automated storage system in order to reduce time and cost related to the extractions. The model was developed during an investigation at a case company, and a comprehensive study of the material handling identified bottlenecks, whereof one was chosen to be further investigated: the automated storage system. The automated storage system is newly installed equipment, which required new working methods to be incorporated to the already existing working environment. The ABC-analysis was used in order to motivate how the articles should be placed in the automated storage. The goal for the new way of handling material was to put as little effort as possible on time related to the extraction of material. This due to the realization of material handling processes being a huge contributor to waste activities. This resulted in the development of the model and the suggestion that is given to the case company is to place the most frequent extracted articles close to the users. However, advantages must be held against disadvantages of rearrangements since the material handling will not be eliminated totally due to smaller improvements.</p> / <p>Syftet med denna uppsats är att skapa en modell för hur man ska organisera artikelplaceringar i ett automatiserat lagersystem för att reducera tid och kostnad relaterat till uttag av material. Modellen skapades genom en undersökning på ett fallföretag, en omfattande studie av materialhanteringen identifierade flaskhalsar, varav en valdes för fortsatt undersökning: det automatiserade lagersystemet. Det automatiserade lagersystemet är en nyinstallerad utrustning, som kräver att nya arbetsmetoder ska inkorporeras till den redan existerande arbetsmiljön. ABC-analysen användes för att motivera hur artiklarna ska placeras i det automatiserade lagret. Målet för det nya sättet att hantera material på var att så få insatser som möjligt skulle användas för uttag av material. Detta pågrund av insikten utav att materialhanteringsprocesser är en stor bidragande slöserifaktor. Detta resulterade i modellen och förslagen som ges till fallföretaget är att placera de mest frekvent använda artiklarna nära användaren. Emellertid så måste man väga fördelar mot nackdelar av en förändring eftersom materialhanteringen inte kommer att elimineras helt pågrund av mindre förbättringar.</p>
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Energy Storage System for Wind-Diesel Power System in Remote LocationsCordeiro, Roberto January 2016 (has links)
The aim of this thesis is to show how much fuel can be saved in a power system based in diesel generators with integrated wind turbine (WDPS – Wind Diesel Power System) when a storage system is integrated. Diesel generator is still the most used power system for remote locations where the conventional grid doesn’t reach and its integration with wind turbine is seen as a natural combination to reduce diesel consumption. However, the wind intermittency brings some challenges that might prevent the necessary diesel savings to the level that justifies the integration with wind turbine. The introduction of a storage system can leverage the wind energy that would otherwise be wasted and use it during periods of high demand.The thesis starts by describing the characteristics of energy storage systems (ESS) and introducing the major ESS technologies: Flywheel, Pumped Hydro, Compressed Air and the four main battery technologies, Lead Acid, Nickel-Based, Lithium-ion and Sodium-Sulphur. The aim of this step it to obtain and compile major ESS parameters to frame then into a chart that will be used as a comparison tool.In the next step, wind-diesel power systems are described and the concept of Wind Penetration is introduced. The ratio between the wind capacity and diesel capacity determines if the wind penetration is low, medium and high and this level has a direct relation to the WDPS complexity. This step also introduces important concepts pertaining to grid load and how they are affected by the wind penetration.Next step shows the development of models for low, medium and high penetration WDPS with and without integrated ESS. Simulations are executed based on these models in order to determine the diesel consumption for each of them. The simulations are done by using reMIND tool.The final step is a comparative study where the most appropriated ESS technology is chosen based on adequacy to the system, system size and location. Once the technology is chosen, the ESS economic viability is determine based on the diesel savings obtained in the previous step.Since this is a general demonstration, no specific data about wind variation and consumer demand was used. The wind variation, which is used as the input for the wind turbine (WT), was obtained from a typical Weibull Distribution which is the kind of distribution that most approximate a wind pattern for long term data collection. The wind variation over time was then randomly generated from this distribution. The consumer load variation is based on a typical residential load curves. Although the load curve was generated randomly, its shape was maintained in conformity with the typical curves.This thesis has demonstrated that ESS integrated to WDPS can actually bring a reasonable reduction in diesel utilization. Even with a wind pattern with a low mean speed (5.31 m/s), the savings obtained was around of 17%.Among all ESS technologies studied, only Battery Energy Storage System (BESS) showed to be a viable technology for a small capacity WDPS. Among the four BESS technologies studied, Lead-Acid presents the highest diesel savings with the lower initial investment and shorter payback time. / O objetivo dessa tese é determinar quanto combustível pode ser economizado quando se integra um sistema de armazenamento de energia (ESS na sigla em Inglês) a um sistema gerador baseado em gerador diesel integrado com turbina eólica (WDPS na sigla em Inglês). Geradores à diesel são largamente utilizados em áreas remotas onde a rede de distribuição de eletricidade não chega, e a integração de geradores à diesel com turbinas eólicas se tornou a combinação usual visando a economia de combustível. No entanto, a intermitência do vento cria alguns desafios que podem inclusive tornar essa integração inviável economicamente. A introdução de ESS à esse sistema visa o aproveitamento da energia que seria desperdiçada para usá-la em periodos de alta demanda.A tese começa descrevendo as características de ESS e suas principais tecnologias: Flyweel, hidroelétrica de bombeamento, ar-comprimido e as quatro principais tecnologias de bateria, Chumbo-Ácido, Níquel, Íon de Lítio e Sódio-Sulfúrico. O objetivo dessa etapa é obter os principais parâmetros de ESS e apresentá-los numa planilha para referência futura.Na etapa seguinte, geradores à diesel são descritos e é introduzido o conceito de Penetração do Vento. A razão entre a capacidade eólica e a capacidade do gerador diesel determina se a penetração é baixa, média ou alta, e esse nível tem uma relação direta com a complexidade do WDPS. Nessa etapa também são introduzidos importantes conceitos sobre demanda numa rede de distribuição de eletricidade e como esta é afetada pela penetração do vento.A etapa seguinte apresenta a modelagem de WDPS com baixa, média e alta penetração, incluindo a integração com ESS. Sobre esses modelos são então executadas simulações buscando determinar o consumo de diesel de cada um. As simulações são feitas usando a ferramenta reMIND.A última etapa é um estudo comparativo para determinar qual tecnologia de ESS é a mais apropriada para WDPS, levando-se em conta sua localização geográfica e capacidade. Uma vez que a escolha tenha sido feita, a viabilidade econômica do ESS é calculada baseado na ecomonia de combustível obtida na etepa anterior.Como esta tese apresenta uma demonstração, não foram utilizados dados reais de variação do vento nem de consumo. A variação do vento foi obtida de uma distribuição Weibull típica, que é a distribuição que mais se aproxima da característica do vento coletada em logo prazo. A variação do vento no tempo foi gerada aleatoriamente baseada nessa distribuição. A curva de consumo é baseada em curvas de consumo residenciais típicas. Embora a curva de consumo tenha sido gerada aleatoriamente, o seu formato foi mantido em conformidade com as curvas típicas.Essa tese demonstrou que ESS integrado à WDPS pode trazer uma economia razoável. Mesmo usando uma distribuição de vento com baixo valor médio (5.3 m/s), a economia obtida foi de 17%.Dentre as tecnologias de ESS pesquisadas, apenas o sistema de armazenamento com bateria (BESS na sigla em Inglês) se mostrou viável para um WDPS com pequena capacidade. Dentre as quatro tecnologias de BESS pesquisadas, Chumbo-Ácido foi a que apresentou a maior economia de diesel com o menor investimento inicial e com o menor tempo de retorno do investimento.
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Étude et modélisation du fonctionnement et du vieillissement des « Lithium-Ion Capacitors » (LiC) / Study and modeling of the functioning and aging of Lithium-ion Capacitors (LiC)El Ghossein, Nagham 06 December 2018 (has links)
Le « Lithium-Ion Capacitor » (LiC) est un supercondensateur hybride dont les caractéristiques peuvent être placées entre un condensateur à double couche électrique (supercondensateur) et une batterie lithium-ion. Il possède des densités d’énergie et de puissance intermédiaires grâce à sa composition hybride à base d'une électrode positive en charbon actif identique à celle d’un supercondensateur et d'une électrode négative en carbone pré-lithié identique à celle d’une batterie lithium-ion. L'objectif de cette thèse est d'étudier le vieillissement des LiC industrialisés aussi bien dans le cadre d’un vieillissement en stockage (calendaire) qu’en utilisation (cyclage). Un de leur spécificité principale concerne l’évolution particulière de leur capacité en fonction de la tension à leurs bornes (C(V)). Le premier type de vieillissement qu’est le vieillissement calendaire permet de représenter le comportement des LiC lorsqu’ils sont stocker avant utilisation ou lorsqu’ils sont en veille. La dégradation de leurs paramètres liée au vieillissement, est alors essentiellement influencée par leur tension et la température. Des essais de vieillissement à trois tensions caractéristiques et deux températures différentes sont étudiés. L’évolution des impédances des cellules a été suivie tout au long du vieillissement afin d’identifier un modèle électrique de suivi du vieillissement dont les paramètres sont liés aux phénomènes électrochimiques. Par ces essais, la meilleure tension de stockage des LiC, permettant la prolongation de leur durée de vie a été mise en évidence. Par ailleurs, des mécanismes de vieillissement différents d’une tension caractéristique à l’autre sont révélés et soulignent la spécificité de fonctionnement des LiC. Ces résultats ont été confirmés par des analyses post-mortem. Le second type de vieillissement étudié est le vieillissement par cyclage qui prend en compte l'impact du courant sur la durée de vie des LiC. Le choix des profils de courant de cyclage a été effectué en considérant le principe de fonctionnement électrochimique des LiC. Les évolutions des impédances et des courbes C(V) des cellules sont comparées et interprétées. Les mécanismes de vieillissement prenant naissance lors du cyclage continu sont abordés. Ils dépendent de la fenêtre de potentiel sur laquelle les LiC fonctionnent pendant leur utilisation. La fenêtre de tension optimale qui assure une longue durée de vie des LiC est aussi mise en évidence / Lithium-Ion Capacitors (LiCs) are the new emerging technology of hybrid supercapacitors that combines the advantages of conventional supercapacitors and lithium-ion batteries. They provide intermediate energy and power densities due to their hybrid composition based on a positive electrode made of activated carbon similar to that of supercapacitors and a negative electrode made of pre-lithiated carbon similar to that of lithium-ion batteries. The aim of this thesis is to study the aging of commercial LiCs using two accelerated aging procedures: calendar aging and cycle aging. One of their main particularities concerns the nonlinear capacitance evolution with respect to their voltage (C(V) curve). The first accelerated aging test is related to the calendar life of LiCs that represents their behavior independently of their usage. The degradation of their parameters due to aging is mainly affected by the voltage and the temperature only. These tests were applied to several cells at three different voltage values and two temperatures. The evolution of their impedances were followed during the whole aging period in order to identify an electrical model that can accurately describe the progress of aging and that possesses electrochemically meaningful parameters. The best voltage value that ensures the extension of the lifetime of LiCs was identified using the results of these tests. In addition, aging mechanisms that extremely depend on the applied voltage value were identified. They highlight the particularity of the functioning of LiCs. These results were confirmed using post-mortem analyses. The second accelerated aging test is the cycle aging that assesses the impact of the current on the life cycle of LiCs. The choice of current profiles was based on the electrochemical operating principle of LiCs. The evolution of the impedances and the C(V) curves of LiCs were compared and analyzed. Aging mechanisms produced during cycle aging were also evaluated. They depend on the voltage range in which the LiC operates. The optimal voltage window that guarantees a long lifetime of LiCs was highlighted
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An empirical study of the technological, organisational and environmental factors influencing South African medical enterprises' propensity to adopt electronic health technologiesMamatela, Motlatsi 06 August 2014 (has links)
Information and communication technologies can be used to deliver healthcare services and improve the healthcare system. Any electronic healthcare system whose usage results in the efficient and enhanced quality of healthcare is an eHealth system and can be beneficial for medical enterprises. Despite the advantages that eHealth systems offer, medical enterprises are often reluctant to abandon their paper-based systems and embrace eHealth solutions.
Through a review of existing eHealth literature, this study identified generic technologies used within South African medical enterprises. Fourteen (14) technologies, that represent a basket of eHealth systems for supporting the business management, professional clinical informatics, patient information storage and consumer health informatics functional areas, were identified. The study then aimed to determine the state of adoption of these technologies as well as the factors influencing adoption. The technological, organisational and environmental (TOE) factors that contributed to the current state of adoption were identified through a review of existing TOE literature. A model that explores the effects of these pre-determined TOE factors on the propensity to adopt eHealth was developed and tested. A cross-sectional, quantitative study was carried out and survey data was collected from a sample of 130 medical enterprises in South Africa. Data was collected using a structured questionnaire. Correlation analysis was used to test the model’s hypotheses and hierarchical regression was used to test the overall TOE model. By using the TOE framework, the study has provided a theoretical contribution and addressed a gap in the literature into the barriers and determinants of the adoption of information and communication technologies (ICTs) in healthcare.
The results of the study show that South African medical enterprises use systems that range from simple electronic fund transfer systems to more complex electronic record and clinical decision support systems. Of the 14 technologies that were identified, business information systems such as medical aid claims submission systems and electronic record systems for patient and fee related information were the most adopted while a steady, but continued increase in the adoption of clinical health information systems was observed. Specifically, the study reveals that electronic fund transfer systems are the most adopted systems while ePrescription systems are the least used. Furthermore, the study shows that in addition to the enterprises’ operating period, perceived benefits, IT infrastructure, senior clinician involvement, resource commitment and external pressure are correlated with the propensity to adopt while system complexity is a barrier to technology adoption.
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Suavização de potência da geração eólica utilizando lógica fuzzy e sistema de armazenamento de energia / Fuzzy logic and energy storage system for wind power smoothingCarvalho, Wilhiam Cesar de 11 April 2019 (has links)
Dentre as diversas fontes de energia renovável que existem atualmente, a energia eólica é a que tem apresentado o maior crescimento nos Sistemas Elétricos de Potência (SEPs). A flutuação de potência da geração eólica, no entanto, tem causado grandes desafios no que diz respeito à Qualidade da Energia Elétrica (QEE) e à operação do SEP. O grande progresso dos Sistemas de Armazenamento de Energia (SAEs), aliado à crescente inserção de geração eólica nos SEPs, tem promovido grande interesse na utilização dos SAEs junto aos aerogeradores. Este trabalho apresenta a utilização de um SAE, conectado ao elo CC do conversor back-to-back do aerogerador, e uma técnica de controle baseada na lógica fuzzy para suavizar as variações da potência de curto prazo da geração eólica. A técnica de controle proposta também é utilizada para gerenciar o Estado de Carga (SOC) do SAE para evitar a condição sobrecarregada e totalmente descarregada. O controle fuzzy é testado e comparado com uma técnica de controle convencional e também com a topologia típica do aerogerador, onde não é utilizado o SAE. As técnicas são avaliadas e comparadas com base em diferentes indicadores numéricos da qualidade da suavização. Um simulador digital em tempo real (RTDSR) é utilizado para realizar as simulações, onde é considerado um aerogerador de 2 MW, um supercapacitor e uma microrrede baseada no benchmark do CIGRÉ de média tensão. Os resultados mostraram que as técnicas de controle do supercapacitor possibilitaram uma adequada suavização de potência da geração eólica e puderam contribuir para a QEE e a operação da microrrede. A técnica inteligente baseada no controlador fuzzy mostrou resultados superiores à técnica convencional e, portanto, apresentou grande potencial para a aplicação. / Among several renewable energy sources existing nowadays, wind energy has presented the largest growth in power systems. The wind power fluctuations, however, has brought great challenges concerning Power Quality (PQ) and power system operation. The great progress of Energy Storage Systems (ESSs), together with the increasing penetration of wind power worldwide, has lead to a great interest in the use of ESS in wind energy. This study presents the application of a ESS, connected to the DC link of the backto- back converter of the wind turbine, and a control technique based on fuzzy logic to smooth out the short-term wind power fluctuations. The proposed control technique is also used to manage the State of Charge (SOC) of the ESS to avoid the overcharged and undercharged states. The fuzzy control is tested and compared with a conventional control technique and also with the typical wind turbine topology, where the ESS is not used. The techniques are evaluated and compared based on different quantitative indicators that represent the quality of the power smoothing. Simulations are carried out in the Real-Time Digital Simulator (RTDSR), where a 2 MW wind turbine, a supercapacitor and a microgrid system based on the CIGRÉ medium voltage benchmark are considered. The results have shown that the control techniques of the supercapacitor permitted a suitable smoothing of the fluctuating wind power and contributed to the microgrid PQ and operation. The intelligent control technique based on the fuzzy logic has shown superior performance compared to the conventional technique and, therefore, presented great potential for application.
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Étude de la fiabilité et du vieillissement d’un système de stockage par supercondensateurs pour l’alimentation partielle et ponctuelle d’un trolleybus grâce à la récupération de l'énergie de freinage : approche du composant au système de stockage / Study of reliability and aging of supercapacitor storage system for partial and punctual supplying of a trolley through the recovery of braking energy : component to the storage system approachKreczanik, Paul 13 April 2011 (has links)
Le premier objectif du projet HYBUS est d’intégrer un système de stockage par supercondensateurs dans un trolleybus permettant la récupération de son énergie de freinage afin d’assurer la continuité de l’alimentation des systèmes électriques embarqués. A terme un système de stockage plus conséquent est prévu pour permettre au trolleybus une autonomie de quelques mètres. Notre travail étudie la durée de vie de ce système. Plusieurs tests de vieillissement accéléré sur les supercondensateurs ont été mis en place au laboratoire AMPERE. Ces essais ont mis en évidence que le cyclage engendrait une forte accélération de la diminution de la capacité et de l’augmentation de la résistance série. Cependant, ces variations sont partiellement réversibles lors des phases de repos où une régénération s’opère. Une méthode se basant sur les dégradations observées en cours d’utilisation et les dégradations demeurant après régénération, a permis une mise en équation de l’évolution des paramètres internes des supercondensateurs. Un test d’endurance de systèmes complets de stockage a aussi été réalisé au laboratoire. Les résultats expérimentaux montrent une hétérogénéité du vieillissement due à l’existence d’importants gradients de température entre les composants. De ce fait, une nouvelle méthodologie d’équilibrage visant à égaliser les durées de vie de chacun des supercondensateurs a été mise au point. L’étude a donc contribué à une meilleure compréhension et évaluation du vieillissement des supercondensateurs dans le but d’améliorer la durée de vie de système de stockage de ce type. Une méthode est proposée pour estimer les dégradations en fonction des facteurs majeurs du vieillissement. / The first objective of the HYBUS project is to integrate a supercapacitor storage system in a trolleybus in order to ensure the continuity of onboard electrical systems supply. The aim is to integrate an energy storage system, composed by a huge number of supercapacitors, for the recovery of the braking energy of trolleybus and allow autonomy for several meters. Our work concerns the study of the lifetime of the storage system. Several accelerated aging tests on supercapacitors were developed in the AMPERE aboratory. These tests have shown that as far as ageing are concerned; the cycling is the major responsible. However, these changes are partially reversible during the rest time when regeneration phenomena are observed. A method based on the observed damage during cycling and the damage after regeneration, leads to a formal equation for the evolution of internal parameters of supercapacitors. An endurance test of complete storage systems was also performed in the laboratory. Experimental results show the heterogeneity of aging due to the existence of significant temperature gradients between components. As a result, a new balancing strategy to equalize the lifetime of each supercapacitors has been developed. In conclusion, our study has contributed to a better comprehension and evaluation of supercapacitors aging in order to improve the lifetime of this type of energy storage system. A method for the estimation of the supercapacitor lifetime has been also proposed.
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Membrane Stratified Solar PondsSchober, Benjamin January 2010 (has links)
<p>This project deals with the potential of membrane stratified solar ponds which consist of two water layers, where one is a salt solution here, and a separating translucent membrane. An experimental pond was set up to study the thermal behaviour of such collector systems. The input is mainly solar radiation, sometimes when the ambient temperatures are higher than the pond temperatures also heat from the environment is transferred into the pond.</p><p>The measured temperatures of the pond, the ambient temperature, the global radiation and wind speed were the basis data for thermal calculations which showed that the pond was working well as a solar collector and thermal storage system all in one. Heat was not extracted from the pond however, only the losses to the environment were studied.</p><p>It was found out that the pond temperatures were higher than the ambient temperature over the whole measurement period of 12 days, and insulation and pollution problems as well as future prospects and suggestions for further studies are discussed at the end of this paper.</p>
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Informed storage management for mobile platformsKim, Hyojun 22 August 2012 (has links)
Storage devices are rapidly changing, and we need to adapt the OS storage software stack to keep up with the changes.
Such a re-evaluation of the storage software stack is especially required for mobile platforms because they are relying on inexpensive flash storage devices having very different performance characteristics from the familiar hard disk.In this thesis work, we first show the importance of storage in mobile platforms; contrary to conventional wisdom, we find evidence that storage is a significant contributor to application performance on mobile devices.
Then, we explore the solution space for flash storage;
user-level library for selective logging, host-side write buffering layer, and OS buffer replacement scheme for flash storage have been studied.
Finally, we build an integrated solution for smartphone storage, named Fjord. In the Fjord study, we re-design logging and RAM buffering solutions for smartphones, and also propose fine-grained reliability control mechanisms. We prove that non-volatile logging can improve storage performance remarkably. Understanding the characteristics of cloud-backed applications and controlling the reliability constraint for chosen cloud-backed applications can achieve additional significant performance gain.We implement and evaluate our solution on a real Android smartphone, and demonstrate significant performance gains for everyday apps on such platforms.
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Membrane Stratified Solar PondsSchober, Benjamin January 2010 (has links)
This project deals with the potential of membrane stratified solar ponds which consist of two water layers, where one is a salt solution here, and a separating translucent membrane. An experimental pond was set up to study the thermal behaviour of such collector systems. The input is mainly solar radiation, sometimes when the ambient temperatures are higher than the pond temperatures also heat from the environment is transferred into the pond. The measured temperatures of the pond, the ambient temperature, the global radiation and wind speed were the basis data for thermal calculations which showed that the pond was working well as a solar collector and thermal storage system all in one. Heat was not extracted from the pond however, only the losses to the environment were studied. It was found out that the pond temperatures were higher than the ambient temperature over the whole measurement period of 12 days, and insulation and pollution problems as well as future prospects and suggestions for further studies are discussed at the end of this paper.
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