Here, we report on a new temperature responsive polymer brush system with a terminal “click” functionality. Bifunctionalized poly(N-isopropylacrylamide) (PNiPAAm) with distinct functional end groups was synthesized by atom transfer radical polymerization (ATRP) and grafted to a modified silicon substrate. The presence of the active terminal alkyne functionality is validated using an azide-modified rhodamine B (N3-RhB) via copper(I) catalyzed alkyne–azide cycloaddition (CuAAC). The optical properties and swelling dynamics of an N3-RhB modified PNiPAAm brush are analyzed in dry state and in situ by VIS-spectroscopic ellipsometry (SE). The best-fit results are obtained using a Gaussian oscillator model and are confirmed by UV/VIS-spectroscopy. We observed evidence of interactions between the aromatic residues of the dye and the PNiPAAm amide groups, which significantly affect the swelling behavior of the modified polymer brush. / Dieser Beitrag ist mit Zustimmung des Rechteinhabers aufgrund einer (DFG-geförderten) Allianz- bzw. Nationallizenz frei zugänglich.

Mechanical pulps are used in paper products such as magazine or news grade printing papers or paperboard. Mechanical pulping gives a high yield; nearly everything in the tree except the bark is used in the paper. This means that mechanical pulping consumes much less wood than chemical pulping, especially to produce a unit area of printing surface. A drawback of mechanical pulp production is the high amounts of electrical energy needed to separate and refine the fibers to a given fiber quality. Mechanical pulps are often produced from slow growing spruce trees of forests in the northern hemisphere resulting in long, slender fibers that are well suited for mechanical pulp products. These fibers have large varieties in geometry, mainly wall thickness and width, depending on seasonal variations and growth conditions. Earlywood fibers typically have thin walls and latewood fibers thick. The background to this study was that a more detailed fiber characterization involving evaluations of distributions of fiber characteristics, may give improved possibilities to optimize the mechanical pulping process and thereby reduce the total electric energy needed to reach a given quality of the pulp and final product. This would result in improved competitiveness as well as less environmental impact. This study evaluated the relation between fiber characteristics in three types of mechanical pulps made from Norway spruce (Picea abies), thermomechanical pulp(TMP), stone groundwood pulp (SGW) and chemithermomechanical pulp (CTMP). In addition, the influence of fibers from these pulp types on sheet characteristics, mainly tensile index, was studied. A comparatively rapid method was presented on how to evaluate the propensity of each fiber to form sheets of high tensile index, by the use of raw data from a commercially available fiber analyzer (FiberLabTM). The developed method gives novel opportunities of evaluating the effect on the fibers of each stage in the mechanical pulping process and has a potential to be applied also on‐line to steer the refining and pulping process by the characteristics of the final pulp and the quality of the final paper. The long fiber fraction is important for the properties of the whole pulp. It was found that fiber wall thickness and external fibrillation were the fibercharacteristics that contributed the most to tensile index of the long fiber fractions in five mechanical pulps (three TMPs, one SGW, one CTMP). The tensile index of handsheets of the long fiber fractions could be predicted by linear regressions using a combination of fiber wall thickness and degree of external fibrillation. The predicted tensile index was denoted BIN, short for Bonding ability INfluence. This resulted in the same linear correlation between BIN and tensile index for 52 samples of the five mechanical pulps studied, each fractionated into five streams(plus feed) in full size hydrocyclones. The Bauer McNett P16/R30 (passed 16 meshwire, retained on a 30 mesh wire) and P30/R50 fractions of each stream were used for the evaluation. The fibers of the SGW had thicker walls and a higher degree of external fibrillation than the TMPs and CTMP, which resulted in a correlation between BIN and tensile index on a different level for the P30/R50 fraction of SGW than the other pulp samples. A BIN model based on averages weighted by each fiber´s wall volume instead of arithmetic averages, took the fiber wall thickness of the SGW into account, and gave one uniform correlation between BIN and tensile index for all pulp samples (12 samples for constructing the model, 46 for validatingit). If the BIN model is used for predicting averages of the tensile index of a sheet, a model based on wall volume weighted data is recommended. To be able to produce BIN distributions where the influence of the length or wall volume of each fiber is taken into account, the BIN model is currently based on arithmetic averages of fiber wall thickness and fibrillation. Fiber width used as a single factor reduced the accuracy of the BIN model. Wall volume weighted averages of fiber width also resulted in a completely changed ranking of the five hydrocyclone streams compared to arithmetic, for two of thefive pulps. This was not seen when fiber width was combined with fiber wallthickness into the factor “collapse resistance index”. In order to avoid too high influence of fiber wall thickness and until the influence of fiber width on BIN and the measurement of fiber width is further evaluated, it is recommended to use length weighted or arithmetic distributions of BIN and other fiber characteristics. A comparably fast method to evaluate the distribution of fiber wall thickness and degree of external fibrillation with high resolution showed that the fiber wallthickness of the latewood fibers was reduced by increasing the refining energy in adouble disc refiner operated at four levels of specific energy input in a commercial TMP production line. This was expected but could not be seen by the use of average values, it was concluded that fiber characteristics in many cases should be evaluated as distributions and not only as averages. BIN distributions of various types of mechanical pulps from Norway spruce showed results that were expected based on knowledge of the particular pulps and processes. Measurements of mixtures of a news‐ and a SC (super calendered) gradeTMP, showed a gradual increase in high‐BIN fibers with higher amounts of SCgrade TMP. The BIN distributions also revealed differences between the pulps that were not seen from average fiber values, for example that the shape of the BINdistributions was similar for two pulps that originated from conical disc refiners, a news grade TMP and the board grade CTMP, although the distributions were on different BIN levels. The SC grade TMP and the SC grade SGW had similar levels of tensile index, but the SGW contained some fibers of very low BIN values which may influence the characteristics of the final paper, for example strength, surface and structure. This shows that the BIN model has the potential of being applied on either the whole or parts of a papermaking process based on mechanical or chemimechanical pulping; the evaluation of distributions of fiber characteristics can contribute to increased knowledge about the process and opportunities to optimize it.

Voltage instability is a major concern in operation of power systems and it is well known that voltage instability and collapse have led to blackout or abnormally low voltages in a significant part of the power system. Consequently, tracking the proximity of the power system to an insecure voltage condition has become an important element of any protection and control scheme. The expected time until instability is a critical aspect. There are a few energy management systems including voltage stability analysis function in the real-time environment of control centres, these are based on assumptions (such as off-line models of the system loads) that may lead the system to an insecure operation and/or poor utilization of the resources. Voltage instability is driven by the load dynamics, and investigations have shown that load restoration due to the on-load tap changer (OLTC) action is the main cause of the voltage instability. However, the aggregate loads seen from bulk power delivery transformers are still the most uncertain power system components, due to the uncertainty of the participation of individual loads and shortcomings of the present approaches in the load modeling. In order to develop and implement a true on-line voltage stability analysis method, the on-line accurate modeling of the higher voltage (supply system) and the lower voltage level (aggregate load) based on the local measurements is required. In this research, using the changes in the load bus measured voltage and current, novel methods are developed to estimate the supply system equivalent and to identify load parameters. Random changes in the load voltage and current are processed to estimate the supply system Thevenin impedance and the composite load components are identified in a peeling process using the load bus data changes during a large disturbance in the system. The results are then used to anticipate a possible long-term voltage instability caused by the on-load tap changer operation following the disturbance. Work on the standard test system is provided to validate the proposed methods. The findings in this research are expected to provide a better understanding of the load dynamics role in the voltage stability, and improve the reliability and economy of the system operation by making it possible to decrease uncertainty in security margins and determine accurately the transfer limits.

Gotland har länge präglats av mycket speciella lösningar och legat i framkant vad gäller ny teknik. Under ca 20 år har Gotland haft en VSC-HVDC-station som har stabiliserat spänningen i det gotländska nätet. HVDC Light har löst en del av de tekniska begränsningarna som hindrat utvecklingen av vindkraftverk. Anläggningen börjar lida mot slutet av sin tekniska livslängd och examensarbetet är ett första steg i utredningen för en eventuell ersättning. Med hjälp av elkvalitetsmätare kartlagdes prestanda och eventuella förbättringsområden. Den svenska stamnätsoperatören Svenska kraftnät har sedan 2016 haft en VSC-HVDC-station som använts för att utväxla energi till asynkrona systemet i Östeuropa. Svenska kraftnät har på senare tid velat utnyttja spänningsregleringsmöjligheterna och utreda mättekniska metoder. Elkvalitetsmätare placerades ut på lämpliga mätpunkter för att utreda anläggningens beteenden. ELSPEC G4500 elkvalitetsmätare installerades på Nordbalt och Gotlands HVDC Light för att mäta under sensommar till hösten 2017. Skillnader mellan CVT och IVT samt Rogowskispole och CT mättes. Valet av ELSPEC lämpade sig bra eftersom att inga triggningsvillkor behövdes som tillåter att man kan upptäcka små men viktiga avvikelser. Gotlands HVDC Light stabiliserar nätet främst mot spänningsdippar efter kortslutningar i 10 kV-elnätet och flimmer ifrån vindkraftsparkerna i ände 2. Märkeffekten för en uppdaterad anläggning kommer baseras på den kortslutningseffekt i 10 kV-nätet som kan utvecklas under anläggningens livstid. Spänningsregleringen ska baseras på en PI-regulator och ska kunna reglera fullt på 40 ms. Komponentspänningar kan användas för att ge reaktiv effekt på de faser som behöver det. Behovet mot flimmer ska baseras på en mätning i närmaste konsumtionscentrum, två mil från ände 2. Om behovet finns, ska en separat loop för flimmerkontroll som motverkar 1,5 Hz-komponenter implementeras utifrån en punkt ca 1,5 mil ifrån ände 2. Teknikvalet står mellan two-level generation 3 eller MMC, beroende på uppgradering eller ersättning. Många olika framtida scenarion påverkar HVDC Lights roll och oavsett, kommer mycket resurser behövas för Gotlands och HVDC Lights framtid. Det har observerats två beteenden på Nordbalt varav ena är långsam och det andra beteendet är snabbt. Det snabba beteendet uppstår när lågohmiga fel sker som också synkronmaskinerna tar hand om. Nordbalt kan hjälpa till för mindre spänningsvariationer om den varit snabbare likt beteendet vid lågohmiga fel. En stabilitetsbedömning behövs dock eftersom att snabbare beteende ökar risken för instabilitet. Eftersom att data mellan CVT och IVT skiljde sig mycket, upplystes mättekniska problem. Några lösningar diskuteras varav RCVT och PQSensor gås igenom grundligt. Alternativa lösningar som MoW och mobila enheter presenteras också vagt. Samtliga lösningar visade sig ha praktiska hinder, vilket försvårar genomförandet. Det uppmanas därför att man bör testa teknikerna i laborationsmiljö eftersom begränsat med studier gjorts på dessa samt att konkurrerande tillverkare uppger olika uppgifter. / Gotland has long been known for various special solutions and been on the leading edge regarding new technology. For the past 20 years Gotland has had a VSC-HVDC station that has stabilized the voltage in the Gotlandic grid. HVDC Light has solved some of the technical limitations that has hindered the growth of wind turbines. The station has almost reached the end of its technical lifespan and the thesis is a first step in the investigation for an eventual replacement. With power quality analyzers performance and improvements were investigated. The Swedish transmission system operator Svenska kraftnät have since 2016 had a VSCHVDC station that have been used to exchange energy to the asynchronous system in Eastern Europe. Svenska kraftnät has of lately wanted to take advantage of the voltage control capabilities and investigate measurement technologies. Power quality analyzers were installed on suitable connection points to investigate the behavior of the station. ELSPEC G4500 power quality analyzers were installed on Nordbalt’s and Gotland’s HVDC Light to measure during the late summer to fall of 2017. The differences between CVT and IVT, and Rogowski coil and CT were captured. The choice of ELSPEC suited well since no trigger conditions are needed which allows small but important errors to be discovered. Gotland’s HVDC Light stabilizes the grid mostly against voltage sags for faults in the 10 kVgrid and flicker from the wind farms in node 2. The rated power for an upgrade should be based on the 10 kV-grid short-circuit power to be developed during the station’s life span. The voltage control should be based on a PI-controller and should be able to transmit full power in 40 ms. Component voltages can be used to produce reactive power on the phases in need. The need against flicker should be based on measurements in the closest center of consumption, 2 miles from node 2. If it’s needed, a separate loop for flicker-control that prevents 1.5 Hz-components based on a point 1.5 mile from node 2 should be implemented. Depending on an upgrade or replacement, the topology can either be “two-level generation 3” or MMC. Many different future scenarios affect HVDC Light’s role and more resources will be required for Gotland’s and HVDC Light’s future. Two behaviors have been observed on Nordbalt where one is slow and the other behavior is fast. The fast behavior was only observed when low impedance faults occurs, that the synchronous generators also handles. Nordbalt can contribute to small voltage variations if it was faster, like the behavior for low impedance faults. A consideration in stability is needed since a faster behavior can lead to stability problems. Since the data between CVT and IVT differed a lot, metrology problems were discovered. Some solutions were discussed, of which RCVT and PQSensor was thoroughly reviewed. Alternative solutions like MoW and mobile units were also presented vaguely. All solutions showed practical difficulties, which complicates the implementation. It is therefore encouraged to test the technologies in a laboratory environment since few studies have been made on these and competing manufactures state different information.

This thesis investigates the period in Judah which took place precisely a century between the death ofHezekiah (687 BCE) and the final fall of Jerusalem (587 BCE) Seldom has a nation experienced so many dramatically sudden reversals of fortune in so relatively short a time. Throughout the first half of the seventh century BCE the Assyrian empire reigned supreme. In the second half, in rapid succession, Judah, as a vassal, experienced periods of independence and of subjection, first to Egypt, then to Babylonia, before finally destroying herself in a futile rebellion against the latter. The aim of the thesis was to set Judah in the global context and investigate the role she played. To this end the Great Powers, namely Assyria, Egypt and Babylonia were surveyed, as well as were the Small Powers, like Judah, Phoenicia and the Transjordanian states, and the relationships probed. The thesis traces the life of the wicked but extraordinarily successful King Manasseh, and his equally reprobate son, Amon, who was brutally murdered by his servants, and was avenged by 'the people of the land'. Josiah is the only monarch who fits the Deuteronomistic requirements of a good king. Religious and national reform generally go hand in hand with politics, and the cultic reform and centralization of the cult characterise his reign. · With the fall of Assyria, the temporary surge into prominence by Egypt and the tragic death of Josiah in 609 BCE, Judah experienced radical political fluctuations and with them alternate subjugation by, and rebellion against, each of the major powers. Inexperienced leadership and a situation of dual kings, followed Josiah's death. The rapidly changing international scene demanded of the rulers of Judah skillful manoeuvring and exceptional adaptability, and frequently confronted them with ominous political situations. Judaean leaders and the puppet King Zedekiah, propped up by false prophets, failed to grasp the shift in the balance of power, and clung to questionable Egyptian aid against the new world power, Babylonia. Highly vulnerable and left in the lurch, Jerusalem faced protracted siege and famine in Jerusalem, destruction ofthe Temple, and deportation ofthe cream ofher people. / Classics and Modern European Languages / D. Litt. et Phil. (Judaica)

Estudamos o diagrama de fases e o ponto tricrítico da transição de colapso em um modelo de animais na rede quadrada, a partir da expansão em série da compressibilidade isotérmica KT do sistema. Como função das variáveis x (fugacidade) e y = e1/T (T é a temperatura reduzida), a serie KT é analisada utilizando-se a técnica dos aproximantes diferenciais parciais. Determinamos o padrão de fluxo das trajetórias características de um típico aproximante diferencial parcial com ponto fixo estável. Obtemos estimativas satisfatórias para a fugacidade tricrítica Xt = 0.024 &#177 0.005 e a temperatura tricritica Tt = 0.54 &#177 0.04. Considerando somente campos de escala lineares, obtemos também o expoente de escala &#947 = 1.4 &#177 0.2 e o expoente \"crossover\" &#934 = 0.66 &#177 0.08. Nossos resultados estão em boa concordância com estimativas prévias obtidas por outros métodos. Também estudamos um processo de polimerização ramifIcada através de simulações computacionais na rede quadrada baseadas em um modelo de crescimento cinético generalizado para se incorporar ramifIcações e impurezas. A configuração do polímero e identificada com uma árvore-ligação (\"bond tree\") a fim de se examinar os aspectos topológicos. As dimensões fractais dos aglomerados (\"clusters\") são obtidas na criticalidade. As simulações também permitem o estudo da evolução temporal dos aglomerados bem como a determinação das auto-correlações temporais e expoentes críticos dinâmicos. Com relação aos efeitos de tamanho finito, uma técnica de cumulantes de quarta ordem e empregada para se estimar a probabilidade de ramificação critica bc e os expoentes críticos v e &#946. Na ausência de impurezas, a rugosidade da superfície e descrita em termos dos expoentes de Hurst. Finalmente, simulamos este modelo de crescimento cinético na rede quadrada utilizando um método de Monte Carlo para estudar a polimerização ramificada com interações atrativas de curto alcance entre os monômeros. O diagrama de fases que separa os regimes de crescimento finito e infinito e obtido no plano (T,b) (T é a temperatura reduzida e b é a probabilidade de ramificação). No limite termodinâmico, extrapolamos a temperatura T&#8727 = 0.102 &#177 0.005 abaixo da qual a fase e sempre infinita. Observamos também a ocorrência de uma transição de rugosidade na superfície do polímero. / The phase diagram and the tricritical point of a collapsing lattice animal are studied through an extended series expansion of the isothermal compressibility KT on a square lattice. As a function of the variables x (fugacity) and y = e1/T (T is the reduced temperature), this series KT is investigated using the partial differential approximants technique. The characteristic flow pattern of partial differential approximant trajectories is determined for a typical stable fixed point. We obtain satisfactory estimates for the tricritical fugacity Xt = 0.024 &#177 0.005and temperature Tt = 0.54 &#177 0.04.Taking into account only linear scaling fields we are also able to get the scaling exponent &#947 = 1.4 &#177 0.2 and the crossover exponent &#934 = 0.66 &#177 0.08. Our results are in good agreement with previous estimates from other methods. We also study ramified polymerization through computational simulations on the square lattice of a kinetic growth model generalized to incorporate branching and impurities. The polymer configuration is identified with a bond tree in order to examine its topology. The fractal dimensions of clusters are obtained at criticality. Simulations also allow the study of time evolution of clusters as well as the determination of time autocorrelations and dynamical critical exponents. In regard to finite size effects, a fourth-order cumulant technique is employed to estimate the critical branching probability be and the critical exponents v and &#946. In the absence of impurities, the surface roughness is described in terms of the Hurst exponents. Finally we simulate this kinetic growth model on the square lattice using a Monte Carlo approach in order to study ramified polymerization with short distance attractive interactions between monomers. The phase boundary separating finite from infinite growth regimes is obtained in the (T,b) space (T is the reduced temperature and b is the branching probability). In the thermodynamic limit, we extrapolate the temperature T = 0.102 &#177 0.005 below which the phase is found to be always infinite. We also observe the occurrence of a roughening transition at the polymer surface.

Les objets numériques 3D sont utilisés dans de nombreux domaines, les films d'animations, la visualisation scientifique, l'imagerie médicale, la vision par ordinateur.... Ces objets sont généralement représentés par des maillages à faces triangulaires avec un nombre énorme de triangles. La simplification de ces objets, avec préservation de la géométrie originale, a fait l'objet de nombreux travaux durant ces dernières années. Dans cette thèse, nous proposons un algorithme de simplification qui permet l'obtention d'objets simplifiés de grande précision. Nous utilisons des fusions de couples de sommets avec une relocalisation du sommet résultant qui minimise une métrique d'erreur. Nous utilisons deux types de mesures quadratiques de l'erreur : l'une uniquement entre l'objet simplifié et l'objet original (Accurate Measure of Quadratic Error (AMQE) ) et l'autre prend aussi en compte l'erreur entre l'objet original et l'objet simplifié ((Symmetric Measure of Quadratic Error (SMQE)) . Le coût calculatoire est plus important pour la seconde mesure mais elle permet une préservation des arêtes vives et des régions isolées de l'objet original par l'algorithme de simplification. Les deux mesures conduisent à des objets simplifiés plus fidèles aux originaux que les méthodes actuelles de la littérature. / Complex 3D digital objects are used in many domains such as animation films, scientific visualization, medical imaging and computer vision. These objects are usually represented by triangular meshes with many triangles. The simplification of those objects in order to keep them as close as possible to the original has received a lot of attention in the recent years. In this context, we propose a simplification algorithm which is focused on the accuracy of the simplifications. The mesh simplification uses edges collapses with vertex relocation by minimizing an error metric. Accuracy is obtained with the two error metrics we use: the Accurate Measure of Quadratic Error (AMQE) and the Symmetric Measure of Quadratic Error (SMQE). AMQE is computed as the weighted sum of squared distances between the simplified mesh and the original one. Accuracy of the measure of the geometric deviation introduced in the mesh by an edge collapse is given by the distances between surfaces. The distances are computed in between sample points of the simplified mesh and the faces of the original one. SMQE is similar to the AMQE method but computed in the both, direct and reverse directions, i.e. simplified to original and original to simplified meshes. The SMQE approach is computationnaly more expensive than the AMQE but the advantage of computing the AMQE in a reverse fashion results in the preservation of boundaries, sharp features and isolated regions of the mesh. For both measures we obtain better results than methods proposed in the literature.

This work presents new analytical and computational methods for operation security assessment of electric power systems by considering Angle and Voltage Stability Limits. In the context of Angle Stability, it was developed a method for estimating transient security margins based on equivalent network reduction techniques and coherent generators. The angle speed deviation was the criterion used to identify generators that swing together. The reduced order was accomplished by replacing two clusters of coherent generators by an One-Machine Infinite Bus equivalent system. With this equivalent, critical fault clearing times and security margins are calculated with the aid of the Equal Area Criterion. The results were in a good agreement when compared with others methods, especially those based on Transient Energy Function used as a Lyapunov function. The method was also applied for estimating security margins and critical fault clearing times of power systems in the presence of wind power generation. It was demonstrated that the proposed method can be used to select critical contingencies, where detailed power system models are needed such that it can reproduce the actual behavior of the system. With respect to Voltage Stability, it was developed an analytical and computational method for steady state voltage stability analysis on a P-Q plane. First of all, it was applied on a simple two-bus power system, and the analytical and computational results were compared. Then, a Voltage Stability Index was derived, in order to obtain the security margins of each bus for any operational state of an n-bus power system. It was carried out by using a power system reduction technique. With the Voltage Stability Index, it is possible to identify critical buses and the regions that are prone to voltage collapse. The voltage stability limits of a distribution power system was also analyzed by means of the P-Q curves, by considering different operation scenarios of wind power generation. It was demonstrated that the wind power can contribute to improve the voltage security margins. Finally, the method was applied to a real power system of Companhia Estadual de Distribuição de Energia Elétrica, in the presence of wind power generation. The methods are computationally efficient and suitable for planning, operation and real-time operation of electric power systems. / Este trabalho apresenta novos métodos analíticos e computacionais para a avaliação da segurança da operação de sistemas elétricos de potência considerando os Limites de Estabilidade Angular e de Tensão. No tema Estabilidade Angular, desenvolveu-se um método para a estimativa de margens de segurança transitória baseado em técnicas de redução de redes e geradores coerentes. O desvio de velocidade angular foi o critério usado para identificar geradores que oscilam juntos. A redução foi realizada substituindo-se dois grupos de geradores coerentes por um sistema Equivalente Máquina-Barra Infinita. Com este equivalente, os tempos críticos de abertura de falta e as margens de segurança são calculados com auxílio do Critério das Áreas Iguais. Os resultados encontrados foram muito satisfatórios quando comparados com aqueles obtidos por outros métodos, especialmente os que utilizam a função energia como função de Lyapunov. O método também foi aplicado para a estimativa de margens de segurança e tempos críticos de abertura de falta, em sistemas de potência na presença de geração eólica. Foi demonstrado que o método proposto é capaz de selecionar contingências críticas que precisam ser estudadas com modelos completos de modo a reproduzir o comportamento real do sistema elétrico. Com relação à Estabilidade Tensão, foi desenvolvido um método analítico e computacional para análise de estabilidade estática de tensão no plano P-Q. Primeiramente, o método foi aplicado em um sistema de potência simples com duas barras, e os resultados analíticos e computacionais foram comparados. Então, um Índice de Estabilidade de Tensão foi deduzido, para determinar a margem de segurança de cada barra para qualquer estado de operação de um sistema de potência com n-barras. Com o Índice de Estabilidade de Tensão, é possível identificar barras críticas e regiões com tendência ao colapso de tensão. Os limites de estabilidade de tensão de um sistema de distribuição foram analisados através das curvas P-Q , no qual foram considerados diferentes cenários de operação da geração eólica. Deste modo, foi demonstrado que a geração eólica pode contribuir para melhorar as margens de segurança de tensão. Finalmente, o método foi aplicado em um sistema de potência real pertencente à Companhia Estadual de Distribuição de Energia Elétrica. Os métodos desenvolvidos são computacionalmente eficientes e adequados para o planejamento da expansão e operação, bem como na operação em tempo real dos sistemas elétricos de potência.

Les comportements critiques des systèmes de mécanique statistique en 2 dimensions ou de mécanique quantique en 1+1 dimensions, ainsi que certains aspects des systèmes sans interactions en 2+1 dimensions, sont efficacement décrits par les méthodes de la théorie des champs conforme et de l'intégrabilité, dont le développement a été spectaculaire au cours des 40 dernières années. Plusieurs problèmes résistent cependant toujours à une compréhension exacte, parmi lesquels celui de la transition entre plateaux dans l'Effet Hall Quantique Entier. La raison principale en est que de tels problèmes sont généralement associés à des théories non unitaires, ou théories conformes logarithmiques, dont la classification se révèle être d'une grande difficulté mathématique. Se tournant vers la recherche de modèles discrets (chaînes de spins, modèles sur réseau), dans l'espoir en particulier d'en trouver des représentations en termes de modèles exactement solubles (intégrables), on se heurte à la deuxième difficulté représentée par le fait que les théories associées sont la plupart du temps non compactes, ou en d'autres termes qu'elles donnent lieu à un continuum d'exposants critiques. En effet, le lien entre modèles discrets et théories des champs non compactes est à ce jour loin d'être compris, en particulier il a longtemps été cru que de telles théories ne pouvaient pas émerger comme limites continues de modèles discrets construits à partir d'un ensemble compact de degrés de libertés, par ailleurs les seuls qui donnent a accès à une construction systématique de solutions exactes.Dans cette thèse, on montre que le monde des modèles discrets compacts ayant une limite continue non compacte est en fait beaucoup plus grand que ce que les quelques exemples connus jusqu'ici auraient pu laisser suspecter. Plus précisément, on y présente une solution exacte par ansatz de Bethe d'une famille infinie de modèles(les modèles $a_n^{(2)}$, ainsi que quelques résultats sur les modèles $b_n^{(1)}$, où il est observé que tous ces modèles sont décrits dans un certain régime par des théories conformes non compactes. Parmi ces modèles, certains jouent un rôle important dans la description de phénomènes physiques, parmi lesquels la description de polymères en deux dimensions avec des interactions attractives et des modèles de boucles impliqués dans l'étude de modèles de Potts couplés ou dans une tentative de description de la transition entre plateaux dans l'Effet Hall par un modèle géométrique compact.On montre que l'existence insoupçonnéede limite continues non compacts pour de tels modèles peut avoir d'importantes conséquences pratiques, par exemple dans l'estimation numérique d'exposants critiques ou dans le résultats de simulations de Monte Carlo. Nos résultats sont appliqués à une meilleure compréhension de la transition theta décrivant l'effondrement des polymères en deux dimensions, et des perspectives pour une potentielle compréhension de la transition entre plateaux en termes de modèles sur réseaux sont présentées. / The critical points of statistical mechanical systems in 2 dimensions or quantum mechanical systems in 1+1 dimensions (this also includes non interacting systems in 2+1 dimensions) are effciently tackled by the exact methods of conformal fieldtheory (CFT) and integrability, which have witnessed a spectacular progress during the past 40 years. Several problems have however escaped an exact understanding so far, among which the plateau transition in the Integer Quantum Hall Effect,the main reason for this being that such problems are usually associated with non unitary, logarithmic conformal field theories, the tentative classification of which leading to formidable mathematical dificulties. Turning to a lattice approach, andin particular to the quest for integrable, exactly sovable representatives of these problems, one hits the second dificulty that the associated CFTs are usually of the non compact type, or in other terms that they involve a continuum of criticalexponents. The connection between non compact field theories and lattice models or spin chains is indeed not very clear, and in particular it has long been believed that the former could not arise as the continuum limit of discrete models built out of acompact set of degrees of freedom, which are the only ones allowing for a systematic construction of exact solutions.In this thesis, we show that the world of compact lattice models/spin chains with a non compact continuum limit is much bigger than what could be expected from the few particular examples known up to this date. More precisely we propose an exact Bethe ansatz solution of an infinite family of models (the so-called $a_n^{(2)}$ models, as well as some results on the $b_n^{(1)}$ models), and show that all of these models allow for a regime described by a non compact CFT. Such models include cases ofgreat physical relevance, among which a model for two-dimensional polymers with attractive interactions and loop models involved in the description of coupled Potts models or in a tentative description of the quantum Hall plateau transition by somecompact geometrical truncation. We show that the existence of an unsuspected non compact continuum limit for such models can have dramatic practical effects, for instance on the output of numerical determination of the critical exponents or ofMonte-Carlo simulations. We put our results to use for a better understanding of the controversial theta transition describing the collapse of polymers in two dimensions, and draw perspectives on a possible understanding of the quantum Hall plateautransition by the lattice approach.

Economic bubbles are playing an increasingly significant role in the current global economy. We believe these bubbles are to a certain extent dominating the real economy, and, therefore, research based on this specific economic phenomenon is becoming increasingly popular and important. The focus of this master's thesis is based upon analysis of stock price bubbles. This thesis contains author analyzed historical cases representative of stock price bubbles; summarizations of their traditional features; common factors causing their formation; and reasons leading to their bursting. Solutions to the dilemma of stock price bubbles are discussed in depth, and emphasis is placed upon clearly deciphering different theoretical approaches regarding this phenomenon-not only from the efficient market hypothesis viewpoint but also from the perspective of behavioral finance. The research contains testing and measuring methodologies of stock price bubbles, and the author's view concerning them is strongly supported by the results within the empirical data-testing chapter. Upon reading, one can expect to achieve a basic overview of this forefront science.