Globular clusters are tracers of the formation and evolution of their host galaxies. Kinematics, chemical abundances, age and position of the clusters allows tracing interactions between Milky Way and surrounding galaxies and outlines their chemical enrichment history. In this thesis we analyse mid-resolution spectra of about 800 red giant stars in 51 Galactic globular clusters. It is the first time that [Fe/H] and [Mg/Fe] derived in a consistent way are published for such a huge sample of globular clusters, almost 1/3 of the total number of catalogued clusters. Our metallicities are showed to be more precise than previous works based on mid-resolution spectroscopy. A turnover at [Fe/H] ~ -1.0 is found in the plot [Fe/H] vs. [Mg/Fe] for bulge and halo, although bulge seems to have a more metal-rich turnover, i.e, bulge has more efficient formation than the halo. Comparing the abundances with age the timescale for SNIa to start to become important is 1Gyr. [Fe/H] vs. age corroborates the different star formation efficiency of bulge and halo while [Mg/Fe] does not follow that. Halo was formed in mini halos or dwarf galaxies, and two multiple population clusters had their origin analysed to check it. M 22 seems to have been formed in the Milky Way while NGC 5824 possibly was originated in a dwarf galaxy, although our results are inconclusive for NGC 5824. The Galactic bulge seems to have been formed fast i.e., probably the oldest globular cluster is there. In fact HP 1 has a bluer horizontal branch than expected for its metallicity and we interpret that as an age effect. We determine its distance using light curves of variable stars in order to constrain future age determinations via colour-magnitude diagram. Finally, we investigate interaction between Milky Way and its neighbour galaxy SMC. We find that some star clusters are being stripped out of the SMC main body, which is consistent with tidal stripping scenario for the interaction between the galaxies, instead of ram pressure that would only affect gas. / Aglomerados globulares são traçadores da formação e evolução de suas galáxias. Cinemática, abundâncias químicas, idades e posições dos aglomerados permitem traçar interações entre Via Láctea e galáxias vizinhas e suas histórias de enriquecimento químico. Nesta tese analisamos espectros de média resolução de mais de 800 estrelas gigantes vermelhas em 51 aglomerados globulares Galácticos. É a primeira vez que [Fe/H] and [Mg/Fe] determinados de modo consistente são publicados para uma amostra desse porte, ~1/3 dos objetos catalogados. Nossas metalicidades são mais precisas que trabalhos anteriores similares. Uma quebra em [Fe/H] ~ -1.0 é encontrada no gráfico [Fe/H] vs. [Mg/Fe] para o bojo e halo, embora bojo parece ter uma quebra em [Fe/H] maior, i.e, bojo tem formaçãao mais eficiente que o halo. Comparando abundâncias com idade, a escala de tempo para SNIa ficar importante é 1Gano. [Fe/H] vs. idade corrobora diferentes eficiências de formação do bojo e halo, mas [Mg/Fe] vs. idade não mostra isso. O halo foi formado em mini halos ou galáxias anãs, e dois aglomerados com dispersão em [Fe/H] tiveram suas origens analisadas. M 22 parece ter sido formado na Via Láctea e NGC 5824 possivelmente foi originado em uma galáxia anã, embora os resultados são inconclusivos para NGC 5824. O bojo parece ter sido formado rapidamente e deve possuir o aglomerado mais velho. De fato, HP 1 tem um ramo horizontal mais azul que o esperado para sua metalicidade e vemos isso como um efeito da idade. Determinamos sua distância usando curvas de luz de RR Lyrae de maneira a restringir futuras determinações de idade via diagrama cor-magnitude. Finalmente, investigamos a interação entre Via Láctea e sua galáxia vizinha SMC. Encontramos aglomerados sendo removidos do corpo central da SMC, consistente com cenário de remoção por força de maré para a interação entre as galáxias, em vez de ``ram pressure\'\' que afeta só gás.

This study explores the experiences of the Swedish front-line social workers (socialsekreterare) in the municipal income support unit, Young Adults, monthly assessing the income support applications as well as daily processing the activation programs for young adult clients with mental ill-health combined with social-medicinal vulnerabilities, also referred to as young adults with complex needs. Furthermore, this study aims to illuminate the ever changing conditions of the Swedish welfare state and its underlying driving forces through the lens of the social workers. 9 Semi-structured distance interviews with 11 social workers from 6 municipalities belonging to 5 regions in Sweden, were conducted for the collection of qualitative data. It has been analyzed by the inductive-deductive coding as well as a theoretical frame consisting of concepts such as discretiona and advocacy of M. Lipsky, and reciprocal interaction (Wechselwirkung), form and contents, and call of G.Simmel. The result and analysis show that the rehabilitative approach based on the interactions and relations with the clients, is prevalent through the social workers’ processing of the activation program. It seems to be effective in a dyad, between the social workers and the client while the social workers’ discretion is maximized for the utilization of the agency (unit) activation resources. However, it proved not to be as effective in a triad or more when an extern agent outside of the unit, Young Adults begins to be involved. The tension is a fact and the social workers’ discretion is minimized when they have to process the activation program for the clients who are neither “active enough” to have a job in the ordinary labor market, nor “sick enough” to be eligible for the stately activity compensation (aktivitetsersättning) from the Social Insurance Agency (Försäkringskassan) which heavily relies on the medicinal expertise for its decision making. The social workers’ experience to fail to deliver the best possible results out of the activation programs, and the client relationship built on the rehabilitative approach turns out to be unsustainable, which can indicate the discrepancy between the rehabilitative approach as well as the activation programs, as content, and the unit, Young Adults, as form. Even though the social workers daily carry the ideological as well as the social-political tensions between the medicalization and the activation through the ever changing reality of the Swedish welfare state, their mandate to make an impact on the decision making of the activity compensation program, is rather limited, reflecting the Swedish welfare state’s expectation for the professionalism of the social workers. Rather striking that the social workers, however, confess that they in spite of the pressure of organizational efficiency as well as socio-economic discourse of digitalization undermining the concept of the unit, Young Adults, are not willing to give up the rehabilitative approach for the client’s sake but also to protect their unit, Young Adults, which postulate that they are not the gatekeepers in the agency but the advocate for the clients. In this moment, they also seem to know, and even have the call, the essential, if not mandatory, element needed to be landed in the perfect society of G. Simmel.

Khyber Pakhtunkhwa (31 ° 49'N, 70 ° 55'E bis 35 ° 50'N, 71 ° 47'E) liegt im Nordwesten Pakistans im Süden Asiens. Das Hindukusch-Gebirge in Afghanistan liegt im Westen, dem indischen Himalaya im Nordosten und die Karakorum Berge südlich vom tibetischen Hochland auf der Nordseite. Diese Arbeit besteht überwiegend aus drei separaten Studien entlang eines 200 km langen Transekts mit einem Höhengradienten ausgehend von den Sedimentbecken im Peshawar Tal (275 m ü.M.) bis hinauf zu den Malam Jabba Hills im Swat-Tal (2600 m ü.M.). Die erste Studie, die auf einer Datengrundlage von 160 Poaceae Arten beruht, zeigt Trends, dass polyploide C3- und C4-Poaceae-Arten größere Pollenkkörner als die jeweiligen diploiden Arten haben. In diesem Datensatz haben alle C4-Arten größere Pollenkörner als die C3-Arten. Ob Grassländer von C3 oder C4 Arten dominiert werden kann in verschiedenen Regionen und Lebensräumen durch die Untersuchung der Muster des Trends von zu- oder abnehmenden Pollenkorngrößen ermittelt werden. In unserem Datensatz ist Polyploidie bei C4-Gräsern häufiger als bei den C3 Arten. Die verwendete Methode kann auf Poaceae-Pollenkörner in Umweltarchiven angewendet werden, um das Klima der Vergangenheit zu rekonstruieren und die Dynamik der früheren Graslandökosysteme zu bewerten. Dieser Ansatz wird nicht nur bei laufenden paläoökologischen Studien helfen aufzuklären, wie die Änderungen der Vegetations-zusammensetzung und die Veränderungen in Biomen vergangener Graslandökosysteme zu entschlüsseln sind, sondern auch nützliche Erkenntnisse für die Vorhersage zukünftiger Entwicklungen ermöglichen. Die zweite Studie befasst sich mit modernen Pollenspektren aus Oberflächenproben und ihre Beziehung zu der umgebenden Vegetation, die nützliche Daten für die Interpretation von holozänen Pollenprofilen bietet. Dabei konnten entlang eines 200 km langen Höhengradienten vier verschiedene Höhenstufen unterschieden werden, wo die dominierenden Pflanzenfamilien, Poaceae, Asteraceae, Cyperaceae, Verbenaceae, Acanthaceae und Euphorbiaceae eine signifikante Korrelation mit dem gefunden Pollenniederschlag hatten, während sich bei anderen Familien, den Boraginaceae, Saxifragaceae, Apiaceae, Balsaminaceae und Rubiaceae große Unterschiede zu der zugehörigen Vegetationszusammensetzung ergaben. Für die Kalibrierung und Interpretation fossiler Pollendaten sollte also immer auch die aktuellen Beziehungen von Pollenniederschlag und Vegetationsdaten zumindest auf der Familienebene berücksichtigt werden. Die dritte Studie befasst sich mit einem Pollenprofil aus der Kabal Swat-Region, welches eine detaillierte Geschichte der Vegetation und des Klimas des Hindukuschs der letzten 3300 Jahre, also dem späten Holozäns enthält. Von 3300 bis 2400 cal BP, war eine subtropische semiaride krautige Vegetation hauptsächlich durch Cyperaceae- und Poaceae-Arten vertreten. Sie wurde ersetzt von gemischten Nadelwäldern mit Taxus, Pinus, sowie Juglans, Poaceae und Cyperaceae während der Zeit von 2400 bis 900 cal BP, was auf eine vergleichsweise moderate Klimaschwankung während des späten Holozäns weist. Der Rückgang der Poaceae von 2400 bis1500 cal BP und eine erneute Zunahme von 1500 bis 1200 cal BP Jahre zeigen, dass das Kabal Swat nass-kühlere und trocken-wärmere Phasen durchmachte. Nadelbäume in den gemischten Nadelwäldern treten heute bei größeren Höhe im alpinen Bereich auf. Weitere hochauflösende holozäne Pollenprofile des Hindukusch sind notwendig, um einen ausführlicheren Vergleich zu anderen süd- und zentralasiatischen Paläo-Archiven zu ermöglichen, die auch ein detaillierteres und anwendbares Wissen für Management und Naturschutzfragen ergeben.

Monolithische Phasen werden seit ca. 20 Jahren entwickelt und sind in den letzten Jahren eine attraktive Alternative zu etablierten mit Partikeln gefüllten Säulen geworden. Sie werden in anorganische Phasen und organische Polymermonolithe unterteilt. Monolithe bestehen aus einem einzigen, durchgehenden Stück. Charakteristisch ist das sie durchziehende Porennetzwerk, durch das der Eluent mit geringerem hydraulischen Widerstand fließen kann und das somit schnellere Flussraten ermöglicht. Polymermonolithe werden vorwiegend für die Separation großer Biomoleküle aufgrund eines durch Konvektion beschleunigten Massentransfers eingesetzt. Zudem sind sie über einen breiten pH-Wert-Bereich stabil und können direkt (in situ) im gewünschten Format polymerisiert werden. In der vorliegenden Arbeit gelang die Herstellung neuartiger epoxidbasierter Phasen nach einem von Weller et al. entwickelten Konzept, die im Affinitätsexperiment angewendet wurden. Die Herstellung erfolgte durch Autopolymerisation polyfunktioneller Glycidylether. Für die Funktionalisierung wurden nicht polymerisierte Epoxide genutzt. Als Monomere dienten TEPIC, GE 100 sowie GE 500. Die Arbeiten konzentrierten sich vor allem auf die bei Raumtemperatur durchführbaren Synthesen mit dem höher funktionellen GE 500. Die Polymerisationsbedingungen wurden hinsichtlich Porogenmischung und -anteil optimiert. Eine mit 75 Vol.-% Porogen (Dioxan/ MTBE (2:3)) hergestellte und mit rProtein A funktionalisierte Kapillarsäule (66 %, 12 µm, 7m2/g) ergab im Affinitätsexperiment eine Kapazität von 0,44 mg/mL aus Kaninchenserum isolierbarem IgG. Durch Beimischung von 60 % BDE konnte der Epoxidgehalt vervierfacht und die Porengröße auf 400 nm bei 59 % Porosität reduziert werden. Die spezifische Oberfläche wurde verdreifacht und die Kapazität präparierter Disks auf 0,90 mg/mL etwa verdoppelt. Die in dieser Arbeit entwickelten Disks können zur Isolierung von IgG aus einer komplexen Probe, wie beispielsweise Blutserum, eingesetzt werden. / Monolithic supports have been developed since 20 years and have become an attractive alternative to well-established columns packed with particles over the past years. They are classified into inorganic media and organic polymer monoliths. Monoliths consist of a single, continuous piece with an integrated characteristic porous network through which the eluent can flow with lower hydraulic resistance and which consequently offers higher flow rates. Due to an accelerated mass transfer caused by convection polymer monoliths are mainly used for separation of large biomolecules. In addition, they are stable over a wide pH range and can be polymerized directly (in situ) in the desired format. In the present work the successful preparation of new epoxide-based supports according to a concept introduced by Weller et al. as well as their application in affinity chromatography are reported. Their preparation was carried out by self-polymerization of polyfunctional glycidyl ethers and for functionalization non-polymerized epoxide groups were used. As monomers TEPIC, GE 100 and GE 500 were utilized. The work has focused especially on the polymerization of the higher functional GE 500, which can be perfomed at room temperature and was optimized in terms of both composition and amount of porogen. The extraction of IgG from rabbit serum with a capillary column (66 %, 12 µm, 7m2/g) prepared by 75 vol.-% porogen (dioxane/ MTBE (2:3)) and functionalized with rprotein A resulted in a capacity of 0,44 mg/mL. By addition of 60 % BDE the epoxide content was quadrupled and the pore size reduced to 400 nm while maintaining consistently high porosity of 59 %. The specific surface area was tripled and the capacity of prepared disks approximately doubled to 0,90 mg/mL. The disks developed in this work can be applied for the isolation of IgG from complex samples such as serum.

Hårdgörning av trä syftar till att göra materialet hårdare. Detta går att åstadkomma genom komprimering, det komprimerade materialet tenderar dock att återgå mot sin ursprungsform då materialet utsätts för fukt om ingen låsning sker. Låsningen kan ske mekaniskt i en treskiktskonstruktion som motverkar träets fuktrörelser. Dessa skivor har dock visat sig vara instabila och tidigare försök har uppvisat deformationer i form av kupning. Denna undersökning syftar till att utreda förutsättningarna för att använda komprimerad asp samt att ta fram underlag för framtagning av en kommersiell produkt. Praktiska tester har genomförts för att studera hårdhet, återfjädring och densitet hos det komprimerade virket. Vidare har treskiktsskivor tagits fram för att testa om det går att få en stabil konstruktion genom att variera tjockleken på spärrskiktet. Även skillnader i acklimatiseringstid och fuktkvotens inverkan för virkets återfjädring har studerats. Resultaten visar på att aspens hårdhet efter komprimering blir i samma nivå som bok och ask, en låg fuktkkvot vid komprimering av materialet ger en låg återfjädring, komprimerat material har en längre acklimatiseringstid till jämviktsfuktkvot och materialet går att låsa tvärs fiberriktningen i en treskiktskonstruktion. / To make wood harder it can be densified. This can be achieved by compression, the compressed material tends to return to the original shape when it is exposed to moisture fluxations and if no form of fixation occurs. The fixation can be done mechanically in a three-layer panel construction which reduce movements in the timber. These panels have been found to be unstable and previous attempts have shown deformations in form of cupping. This study aims to evaluate the conditions for using compressed aspen wood, and to provide a basis for development of a commercial product. Practical tests have been conducted to study hardness, springback and density of the compressed wood. In addition, three-layer panels have been developed to test whether it is possible to have a stable construction by varying the thickness of the buttom layer. Differences in acclimatisation time and the moisture contents effect on the springback has aslo been studied. The results show that the hardness of aspen wood after compression is in equal levels with beech and ashes, a low moisture contet provides a low springback, compressed timber have a longer time for acclimatisation and it is possible to fixate the material in the direction across the grain in a three-layer panel construction.

<p>Hårdgörning av trä syftar till att göra materialet hårdare. Detta går att åstadkomma genom komprimering, det komprimerade materialet tenderar dock att återgå mot sin ursprungsform då materialet utsätts för fukt om ingen låsning sker. Låsningen kan ske mekaniskt i en treskiktskonstruktion som motverkar träets fuktrörelser. Dessa skivor har dock visat sig vara instabila och tidigare försök har uppvisat deformationer i form av kupning. Denna undersökning syftar till att utreda förutsättningarna för att använda komprimerad asp samt att ta fram underlag för framtagning av en kommersiell produkt.</p><p>Praktiska tester har genomförts för att studera hårdhet, återfjädring och densitet hos det komprimerade virket. Vidare har treskiktsskivor tagits fram för att testa om det går att få en stabil konstruktion genom att variera tjockleken på spärrskiktet. Även skillnader i acklimatiseringstid och fuktkvotens inverkan för virkets återfjädring har studerats.</p><p>Resultaten visar på att aspens hårdhet efter komprimering blir i samma nivå som bok och ask, en låg fuktkkvot vid komprimering av materialet ger en låg återfjädring, komprimerat material har en längre acklimatiseringstid till jämviktsfuktkvot och materialet går att låsa tvärs fiberriktningen i en treskiktskonstruktion.</p> / <p>To make wood harder it can be densified. This can be achieved by compression, the compressed material tends to return to the original shape when it is exposed to moisture fluxations and if no form of fixation occurs. The fixation can be done mechanically in a three-layer panel construction which reduce movements in the timber. These panels have been found to be unstable and previous attempts have shown deformations in form of cupping. This study aims to evaluate the conditions for using compressed aspen wood, and to provide a basis for development of a commercial product.</p><p>Practical tests have been conducted to study hardness, springback and density of the compressed wood. In addition, three-layer panels have been developed to test whether it is possible to have a stable construction by varying the thickness of the buttom layer. Differences in acclimatisation time and the moisture contents effect on the springback has aslo been studied.</p><p>The results show that the hardness of aspen wood after compression is in equal levels with beech and ashes, a low moisture contet provides a low springback, compressed timber have a longer time for acclimatisation and it is possible to fixate the material in the direction across the grain in a three-layer panel construction.</p>

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No description available.