Im Rahmen dieser Arbeit wurden die Kondo-Gitter YbT2Si2 (T = Rh, Ir, Co) und CeTPO (T = Ru, Os, Fe, Co) untersucht. In diesen Systemen treten starke ferromagnetische Korrelationen der 4f-Momente zusammen mit ausgeprägter Kondo-Wechselwirkung auf, deren theoretische Beschreibung bislang sehr kontrovers diskutiert wird. Diese Arbeit liefert damit einen essentiellen experimentellen Beitrag zur Physik von ferromagnetischen Kondo-Gittern. So konnten qualitativ hochwertige Einkristalle von YbRh2Si2 hergestellt und erstmalig an einem Schwere-Fermion-System deren kritische Fluktuationen um den magnetischen Phasenübergang analysiert werden. Weiterhin konnte das bis dahin unverstandene Auftreten einer Elektron-Spin-Resonanz (ESR)-Linie in YbT2Si2 auf ferromagnetische Korrelationen zurückgeführt werden. Außerdem wurde mit CeFePO ein neues Schwere-Fermion-System mit starken ferromagnetischen Korrelationen entdeckt sowie mit dem isoelektronischen CeRuPO der seltene Fall eines ferromagnetisch geordneten Kondo-Gitters realisiert. / Within the context of this thesis the Kondo lattices YbT2Si2 (T = Rh, Ir, Co) and CeTPO (T = Ru, Os, Fe, Co) were investigated. In these systems strong ferromagnetic correlations of the 4f-moments together with pronounced Kondo interactions are present, whose theoretical description are pres-ently controversial discussed. Therefore, this work gives an essential experimental contribution to the physics of ferromagnetic Kondo lattices. The main results include the growth of high-quality single crystals of YbRh2Si2 and the first analysis of the critical fluctuations around the magnetic phase transition in a heavy fermion system. Furthermore, the unexpected observation of an electron spin resonance in YbT2Si2 could be ascribed to ferromagnetic correlations. Moreover, a new heavy fermion system CeFePO with strong ferromagnetic correlations was found and with the isoelec-tronic CeRuPO the rare case of a ferromagnetic Kondo-lattice discovered.

No description available.

No description available.

No description available.

Im Rahmen dieser Arbeit wurden die Kondo-Gitter YbT2Si2 (T = Rh, Ir, Co) und CeTPO (T = Ru, Os, Fe, Co) untersucht. In diesen Systemen treten starke ferromagnetische Korrelationen der 4f-Momente zusammen mit ausgeprägter Kondo-Wechselwirkung auf, deren theoretische Beschreibung bislang sehr kontrovers diskutiert wird. Diese Arbeit liefert damit einen essentiellen experimentellen Beitrag zur Physik von ferromagnetischen Kondo-Gittern. So konnten qualitativ hochwertige Einkristalle von YbRh2Si2 hergestellt und erstmalig an einem Schwere-Fermion-System deren kritische Fluktuationen um den magnetischen Phasenübergang analysiert werden. Weiterhin konnte das bis dahin unverstandene Auftreten einer Elektron-Spin-Resonanz (ESR)-Linie in YbT2Si2 auf ferromagnetische Korrelationen zurückgeführt werden. Außerdem wurde mit CeFePO ein neues Schwere-Fermion-System mit starken ferromagnetischen Korrelationen entdeckt sowie mit dem isoelektronischen CeRuPO der seltene Fall eines ferromagnetisch geordneten Kondo-Gitters realisiert. / Within the context of this thesis the Kondo lattices YbT2Si2 (T = Rh, Ir, Co) and CeTPO (T = Ru, Os, Fe, Co) were investigated. In these systems strong ferromagnetic correlations of the 4f-moments together with pronounced Kondo interactions are present, whose theoretical description are pres-ently controversial discussed. Therefore, this work gives an essential experimental contribution to the physics of ferromagnetic Kondo lattices. The main results include the growth of high-quality single crystals of YbRh2Si2 and the first analysis of the critical fluctuations around the magnetic phase transition in a heavy fermion system. Furthermore, the unexpected observation of an electron spin resonance in YbT2Si2 could be ascribed to ferromagnetic correlations. Moreover, a new heavy fermion system CeFePO with strong ferromagnetic correlations was found and with the isoelec-tronic CeRuPO the rare case of a ferromagnetic Kondo-lattice discovered.

Uppsatsen syftar till att studera intertextualiteten i Bjarne Moelvs Helgas offer – dagboksroman om ett brott och Hjalmar Söderbergs Doktor Glas. Tyngden i analysen ligger på Moelvs roman, under det att Doktor Glas tjänar som belysande jämförelsematerial. Analysen består av tre delar där den textuella strukturen, perspektivet och berättarstrukturen undersöks. Resultaten visar att romanerna uppvisar flera stilistiska likheter men även tydliga skillnader när det gäller jagberättarens framställning. Moelv distanserar sig från det kvinnliga berättarjaget genom att begränsa henne till en iakttagare. Detta ger uttryck för en framställning som konstrueras ur ett genussystem där manliga normer slår igenom i representationer av kvinnor.

In this thesis, a miniaturized energy harvester system is developed. The energy harvester converts fluid kinetic energy into electrical energy without using any rotating components. The working principle of the energy harvester is based on the so called vortex-induced vibration. Such systems have the potential to provide energy for wireless sensor networks in the field of inline measurements for gas, oil or water transportation systems. The theoretical background of the vortex-induced vibration (VIV) is studied. Based on the studies, a fluid-structure interaction simulation is carried out to optimize the structure of the energy harvester. As result, the conversion efficiency is significantly improved, which is experimentally confirmed. A series of demonstrators are manufactured according to the simulation and optimization results. It is tested on a self-constructed test bench. To further improve the performance, an electromagnetic generator is proposed, and therefore, a multimethod demonstrator realized. The demonstrators are working in air flow already at a velocity of 2 m/s, and reach the maximum efficiency at 3.6 m/s. This performance ranks among the best published results and is discussed in detail. / In der vorliegenden Arbeit wird ein miniaturisiertes Energiegewinnungssystem entwickelt, das unter Verzicht auf rotierende Komponenten kinetische Strömungsenergie in elektrische Energie umwandelt. Die Funktion dieses Wandlers basiert auf der sogenannten wirbelinduzierten Vibration. Derartige Systeme besitzen unter anderem das Potenzial, drahtlose Sensornetzwerke zur Erfassung von Messdaten in Gas-, Öl- oder Wassertransportsystemen mit Energie zu versorgen zu können. In der Arbeit wird der theoretische Hintergrund der wirbelinduzierten Vibration untersucht und darauf basierend werden Fluid-Struktur-Wechselwirkungssimulationen zur Strukturoptimierung durchgeführt in deren Ergebnis eine theoretische Verbesserung der Effizienz des Wandlers um ein Mehrfaches erreicht wird, die auch praktisch bestätigt wird. Unter Berücksichtigung der Simulations- und Optimierungsergebnisse wurden eine Reihe von Demonstratoren gefertigt, die auf einem selbst konstruierten Prüfstand getestet wurden. Zur weiteren Erhöhung der Leistungsfähigkeit des Wandlers wird ein zusätzlicher elektromagnetischer Generator vorgeschlagen und damit ein Multi-Methoden-Demonstrator technisch realisiert. Die Demonstratoren arbeiten in strömender Luft bereits bei Geschwindigkeiten von 2 m/s und erreichen bei 3,6 m/s ihre maximale Effizienz. Die erreichten Ergebnisse ordnen sich im Vergleich mit denen aus entsprechenden Publikationen vorn ein und werden ausführlich diskutiert.

In this thesis, a series of computational studies based on density functional theory (DFT) and density functional tight-binding (DFTB) is presented to deeply understand experimental results on the synthesis of endohedral fullerenes and graphene/iron hybrids at atomic level. In the first part, a simple and efficient model is proposed to evaluate the strain experienced by clusters encapsulated in endohedral metallofullerenes (EMFs). Calculations for the sole cluster, either in the neutral or the charged state, cannot be used for this goal. However, when the effect of the carbon cage is mimicked by small organic π-systems (such as pentalene and sumanene), the cluster has sufficient freedom to adopt the optimal configuration, and therefore the energetic characteristics of the EMF-induced distortion of the cluster can be evaluated. Both nitride and sulfide clusters were found to be rather flexible. Hence, they can be encapsulated in carbon cages of different size and shape. For carbide M2C2 cluster the situation is more complex. The optimized cluster can adopt either butterfly or linear shapes, and these configurations have substantially different metal-metal distance. Whereas for Sc2C2 both structures are isoenergetic, linear form of the Y2C2 cluster is substantially less stable than the butterfly-shaped configuration. These results show that phenomenon of the “nanoscale fullerene compression” once proposed by Zhang et al. (J. AM. CHEM. SOC. (2012),134(20)) should be “nanoscale fullerene stretching”. Finally, the results also reveal that both Ti2S and Ti2C2 cluster are strained in corresponding EMF molecules, but the origin of the strain is opposite: C78-D3h(5) cage imposes too long Ti···Ti distance for the sulfide cluster and too short distance for the carbide cluster. In the second part of the thesis, possible fullerene geometries and electronic structures have been explored theoretically for the species detected in mass spectra of the Sc-EMF extract synthesized using CH4 as a reactive gas. Two most promising candidates, namely Sc4C@C80-Ih(7) and Sc4C3@C80-Ih(7), have been identified and further studied at the DFT level. For Sc4C@C80, the tetrahedral Sc4 cluster with the central μ4-C atom was found to be 10 kJ/mol more stable than the square cluster. For Sc4C3@C80, the calculation showed that the most stable is the Sc4C3 cluster in which the triangular C3 moiety is η3- and η2-coordinated to Sc atoms. Whereas Sc4C@C80 has rather small HOMO-LUMO gap and low ionization potential, the HOMO-LUMO gap of Sc4C3@C80 is substantially higher and exceeds that of Sc4C2@C80. In the third part, computational studies of structures and reactivity are described for a new type of EMFs with a heptagon that has been produced in the arc-discharge synthesis. DFT computations predict that LaSc2N@Cs(hept)-C80 is more stable than LaSc2N@D5h-C80, so the former should be synthesized in much higher yield than observed. This disagreement may be ascribed to the kinetic factors rather than thermodynamic stability. Because of prospective applications of this EMFs by introducing functional groups, the influence of the heptagon on the chemical properties have been further evaluated. Thermodynamically and kinetically preferred reaction sites are studied computationally for Prato and Bingel-Hirsch cycloaddition reactions. In both types of reactions the heptagon is not affected, and chemical reactivity is determined by the adjacent pentalene units. Thermodynamically controlled Prato addition is predicted to proceed regioselectively across the pentagon/pentagon edges, whereas the most reactive sites in kinetically-controlled Bingel-Hirsch reaction are the carbon atoms next to the pentagon/pentagon edge. Fourth, although various EMFs have been successfully synthesized and characterized, the formation mechanism is still not known in details, and hence control of the synthesis products is rather poor. Therefore, EMF self-assembly process in Sc/carbon vapor in the presence and absence of cooling gas (helium) and reactive gas (NH3 and CH4) is systematically investigated using quantum chemical molecular dynamics (QM/MD) simulations based on the DFTB potentials. The cooling gas effect is that the presence of He atoms accelerates formation of pentagons and hexagons and reduces the size of formed carbon cages in comparison to the analogous He-free simulations. As a result, the Sc/C/He system yields a large number of successful trajectories (i.e. leading to the Sc-EMFs) with more realistic cage-size distribution than the Sc/C system. Encapsulation of Sc atoms within the carbon cage was found to proceed via two parallel mechanisms. The main mechanism involves nucleation of the several hexagons and pentagons with Sc atoms already at the early stages of the carbon vapor condensation. In such proto-cages, both Sc–C σ-bonds and coordination bonds between Sc atoms and the π-system of the carbon network are present. Sc atoms are thus rather labile and can move along the carbon network, but the overall bonding is sufficiently strong to prevent dissociation even at high temperatures. Further growth of the carbon cage results in encapsulation of one or two Sc atoms within the forming fullerene. Another encapsulation mechanism is observed in rare cases. In this process, the closed cage is formed with Sc being a part of the carbon network, i.e. being bonded by three or four Sc–C σ-bonds. However, such intermediates are found to be unstable, and transform into the endohedral fullerenes within few picoseconds of annealing. In perfect agreement with experimental studies, extension of the simulation to Fe and Ti showed that Fe-EMFs are not formed at all, whereas Ti is prone to form Ti-EMFs with small cage sizes, including Ti@C28-Td and Ti@C30-C2v(3). The role of “reactive gas” in the EMF synthesis is revealed in dedicated simulations of the fullerene formation in the presence of several molecules of CH4 or NH3. When concentration of reactive gas is high, carbon vapor tends to form graphene flakes or other carbon species terminated by hydrogen atoms, whereas the yield of empty fullerenes is very low. Conversely, with additional metal atoms (Sc) and the same number of NH3 molecules, the yield of fullerenes constantly increase from 5 to 65% which is ascribed to the catalytic activity of metal atoms in the nucleation of carbon cages already at early stage. Moreover, due to the presence of hydrogen atoms from the reactive gas, the carbon cage formation requires much longer time, which provides sufficient reaction time to encapsulate 3 or 4 Sc atoms within one cage. It explains preferential formation of clusterfullerenes in experiments with reactive gas. At the same time, monometallofullerenes and dimetallofullerenes are the main products in absence of reactive gas. We also provide possible growth mechanisms of carbide and cyano-clusterfullerenes in details to elucidate how the intracluster goes into the cage. A possible growth mechanism of nitride clusterfullerenes has been proposed based on DFT results. In the last part, a free-standing crystalline single-atom thick layer of Fe has been studied theoretically. By investigating the energy difference, ΔE, between a suspended Fe monolayer and a nanoparticle using the equivalent number of Fe atoms, one can estimate that the largest stable membrane should be ca. 12 atoms wide or 3 × 3 nm2 which is in excellent agreement with the experimental observation. Otherwise, the possibility of C, O, N atoms embedded into the Fe membrane can been fully excluded by DFTB and DFT simulations, which agrees with electron energy loss spectroscopy (EELS) measurement. A significantly enhanced magnetic moment for single atom thick Fe membranes (3.08 μB) is predicted by DFT as compared to the bulk BCC Fe (2.1 μB), which originates from the 2D nature of the Fe membrane since the dz2 orbital is out-of-plane while the dxy orbital is in-plane.

Produktutveckling är en generellt riskfylld bransch med stora investeringar och många saker som kan gå fel under projektens gång. Genom att tidigt i projekt identifiera risker och problemområden är det också lättare att undvika att problem uppstår. Under detta examensarbete studerades tre svenska företags riskhanteringsprocess genom intervjuer av projektledare på företagen. Detta examensarbete redogör också för aktuell forskning inom riskhantering men fokuserar även på organisatoriskt lärande och vikten av kundkrav, kopplat till risker i produktutvecklingsprojekt. Målet med arbetet var att föreslå olika förbättrings- och implementeringsmöjligheter för företag i deras riskhanteringsarbete med avseende på deras befintliga produktutvecklingsprocess. Det som framkommit under denna studie tyder på att en stor förståelse av kundkrav, kombinerat med en tydlig projektstruktur och arbete med organisatoriskt lärande, kan användas för att identifiera och minimera risker i produktutvecklingsprojekt. När kundkrav är uttryckt i mätbara variabler kan dessa kommuniceras så att alla inblandade har samma förväntningar på projektet vilket då leder till en minskad osäkerhet och färre risker. Studien tyder på att det finns många krav som är svåra att definiera, men när organisationen arbetar aktivt för att bevara och sprida definitioner av kundkrav som de stött på i tidigare projekt kan missuppfattningar minska och tidsbesparingar göras. Genom att ha en tydlig struktur och projektprocess är det också möjligt att implementera lärdomar i organisationen, där företag kan använda befintliga system och avstämningsmöten för att bevara och sprida kunskap. / Product development is a generally risky business with great investments and numerous things that can go wrong during the projects. By defining risks and problem areas early in the projects, the occurrence of problems can be avoided. During this bachelor thesis the risk handling process of three Swedish companies were studied by interviewing project managers working there. This report also accounts for current research within risk management, as well as organizational learning and the importance of customer demands, in relation to risks in product development projects. The aim for this bachelor thesis was to give suggestions on how companies can improve their risk handling in regards to their existing product development process. This study indicates that a great understanding of customer demands, combined with a clear project structure and organizational learning, can be used to identify and minimize risks in product development projects. When the customer demands are expressed using metric variables they can also be communicated to the team so that everyone involved have the same expectations on the project, which leads to reduced uncertainties and fewer risks. The study indicates that many demands are difficult to define, but when the organization actively works to preserve and distribute definitions of customer demands that they have previously encountered, it leads to fewer misconceptions and helps reduce project delays. By using a clear structure and project process it is also possible to implement lessons learned into the organization, using existing systems and scheduled meetings as a way to preserve and distribute knowledge.

No description available.