Основными технологическими и трудно определяемыми примесями в h-BN выступают углерод и кислород. На производстве возникает необходимость в контроле качества с высоким пространственным разрешением как отдельных нанослоев h-BN, так и готовых гетероструктур на его основе. Целью работы является разработка способа неразрушающего контроля дефектности и примесного состава тонких слоев h-BN методами комбинационного рассеяния света и катодолюминесцентной спектрометрии. Выполнен литературный обзор особенностей материала гексагонального нитрида бора и его люминесцентных свойств. Проведены измерения исследуемых образцов при помощи рамановского спектрометра, сканирующего электронного микроскопа с катодолюминесцентной приставкой и электронно-зондового микроанализатора. Выполнен анализ полученных результатов. / The main technological and difficult-to-determine impurities in h-BN are carbon and oxygen. In production, there is a need for quality control with high spatial resolution of both individual h-BN nanolayers and heterostructures based on it. The aim of the work is to develop a method for non-destructive testing of the defects and impurity composition of h-BN thin layers by Raman scattering and cathodoluminescence spectrometry. A literature review of the features of the material of hexagonal boron nitride and its luminescent properties is performed. The samples were measured using a Raman spectrometer, a scanning electron microscope with a cathodoluminescent attachment, and an electron probe microanalyzer. The analysis of the obtained results is performed. Areas of application: diagnostics and quality control.

Nous avons utilisé la méthode de CEMOVIS (Cryo-Electron Microscopy Of Vitreous Sections) pour étudier l’ultrastructure des cellules HT29 (lignée cancéreuse colique humaine) et plus particulièrement l’organisation de la chromatine au sein du noyau. Pour améliorer la méthode, nous avons développé un micromanipulateur qui facilite la collecte des coupes et leur transfert sur la grille. Nous avons également cherché à préparer de nouveaux films métalliques (en remplacement du carbone) permettant une meilleure adhésion des coupes sur le support Au vu des premiers tests réalisés, les films de TiO2 que nous avons fabriqués au laboratoire et caractérisés par microscopie électronique (HR, spectroscopie et cartographie EELS) semblent offrir des perspectives intéressantes que nous attribuons à leur propriétés de conducteur électrique à basse température (ce qui reste à démontrer). Les organites cellulaires (noyaux, réseaux de filaments du cytosquelette, systèmes multilamellaires) ont été identifiés in situ. Les conditions d’imagerie choisies nous ont permis d’obtenir une résolution permettant d’identifier les deux feuillets des bicouches membranaires. Dans le noyau, nous avons observé des motifs striés, distants de 2.7 à 3.5 nm que nous attribuons à la molécule d’ADN enroulée autour du cœur d’histones. Comparées aux images de phases denses de nucléosomes, ces images suggèrent que les nucléosomes (jamais identifiés in situ jusqu’à présent) présentent un ordre très local au sein de la chromatine, que nous discutons à la lumières des modèles polymériques actuels. / The ultrastructure of HT29 cells (human epithelial adenocarcinoma cell line) was studied by CEMOVIS (Cryo-Electron Microscopy of Vitreous Sections) with a special emphasis on chromatin organization in the cell nucleus. We proposed methodological improvements for this technique:- We first developed a grid holding micromanipulator to facilitate both cryosections collect and deposition on carbon-coated TEM grids.- We also developed new metallic thin films (to replace carbon-base supports) to enhance the adhesion of cryosections on their support. The TiO2 thin films that we produced and analysed by electron microscopy (high resolution imaging, EELS and chemical mapping) seem to be an interesting alternative to carbon films for the deposition of cryosections. Their adhesive properties could be due to Titanium high electric conductance at low temperature (although this relation has not been clearly demonstrated yet).In HT 29 cells, we indentified cell organites (nucleus; cytoskeleton filament bundles, multilamellar bodies) in situ. Selected imaging conditions provide for a high enough resolution to visualise the two membrane leaflets. In the cell nucleus, we observed striated patterns separated from 2.7 to 3.5 nm that we assume to be DNA molecule turns wrapped around the histone protein core. Compared with the dense phases formed in vitro by nucleosome core particle in solution, our images suggest that nucleosomes are locally ordered in chromatin. This observation is discussed regarding the chromatin polymeric models.

Wir untersuchen globale dynamische Phänomene, die sich von dem Zusammenspiel zwischen Netzwerktopologie und Dynamik der einzelnen Elementen ergeben. Im ersten Teil untersuchen wir relativ kleine strukturierte Netzwerke mit überschaubarer Komplexität. Als geeigneter theoretischer Rahmen für erregbare Systeme verwenden wir das Kuramoto und Shinomoto Modell der sinusförmig-gekoppelten "aktiven Rotatoren" und studieren das Kollektivverhalten des Systems in Bezug auf Synchronisation. Wir besprechen die Einschränkungen, die durch die Netzwerktopologie auf dem Fluss im Phasenraum des Systems gestellt werden. Insbesondere interessieren wir uns für die Stabilitätseigenschaften von Fluss-invarianten Polydiagonalen und die Entwicklungen von Attraktoren in den Parameterräume solcher Systeme. Wir untersuchen zweidimensionale hexagonale Gitter mit periodischen Randbedingungen. Wir untersuchen allgemeine Bedingungen auf der Adjazenzmatrix von Netzwerken, die die Watanabe-Strogatz Reduktion ermöglichen, und diskutieren verschiedene Beispiele. Schließlich präsentieren wir eine generische Analyse der Bifurkationen, die auf der Untermannigfaltigkeit des Watanabe-Strogatz reduzierten Systems stattfinden. Im zweiten Teil der Arbeit untersuchen wir das globale dynamische Phänomen selbstanhaltender Aktivität (self-sustained activity / SSA) in neuronalen Netzwerken. Wir betrachten Netzwerke mit hierarchischer und modularer Topologie , umfassend Neuronen von verschiedenen kortikalen elektrophysiologischen Zellklassen. Wir zeigen, dass SSA Zustände mit ähnlich zu den experimentell beobachteten Eigenschaften existieren. Durch Analyse der Dynamik einzelner Neuronen sowie des Phasenraums des gesamten Systems erläutern wir die Rolle der Inhibierung. Darüber hinaus zeigen wir, dass beide Netzwerkarchitektur, in Bezug auf Modularität, sowie Mischung aus verschiedenen Neuronen, in Bezug auf die unterschiedlichen Zellklassen, einen Einfluss auf die Lebensdauer der SSA haben. / In this work we study global dynamical phenomena which emerge as a result of the interplay between network topology and single-node dynamics in systems of excitable elements. We first focus on relatively small structured networks with comprehensible complexity in terms of graph-symmetries. We discuss the constraints posed by the network topology on the dynamical flow in the phase space of the system and on the admissible synchronized states. In particular, we are interested in the stability properties of flow invariant polydiagonals and in the evolutions of attractors in the parameter spaces of such systems. As a suitable theoretical framework describing excitable elements we use the Kuramoto and Shinomoto model of sinusoidally coupled “active rotators”. We investigate plane hexagonal lattices of different size with periodic boundary conditions. We study general conditions posed on the adjacency matrix of the networks, enabling the Watanabe-Strogatz reduction, and discuss different examples. Finally, we present a generic analysis of bifurcations taking place on the submanifold associated with the Watanabe-Strogatz reduced system. In the second part of the work we investigate a global dynamical phenomenon in neuronal networks known as self-sustained activity (SSA). We consider networks of hierarchical and modular topology, comprising neurons of different cortical electrophysiological cell classes. In the investigated neural networks we show that SSA states with spiking characteristics, similar to the ones observed experimentally, can exist. By analyzing the dynamics of single neurons, as well as the phase space of the whole system, we explain the importance of inhibition for sustaining the global oscillatory activity of the network. Furthermore, we show that both network architecture, in terms of modularity level, as well as mixture of excitatory-inhibitory neurons, in terms of different cell classes, have influence on the lifetime of SSA.

Nanomaterials, typically less than 100 nm size in any direction have gained noteworthy interest from scientific community owing to their significantly different and often improved physical properties compared to their bulk counterparts. Semiconductor nanoparticles (NPs) are of great interest to study their tunable optical properties, primarily as a function of size and shape. Accordingly, there has been a lot of attention paid to synthesize discrete semiconducting nanoparticles, of where Group III-V and II-VI materials have been studied extensively. In contrast, Group IV and Group IV-V based nanocrystals as earth abundant and less-non-toxic semiconductors have not been studied thoroughly. From the class of Group IV, Ge1-xSnx alloys are prime candidates for the fabrication of Si-compatible applications in the field of electronic and photonic devices, transistors, and charge storage devices. In addition, Ge1-xSnx alloys are potentials candidates for bio-sensing applications as alternative to toxic materials. Tin phosphides, a class of Group IV-V materials with their promising applications in thermoelectric, photocatalytic, and charge storage devices. However, both aforementioned semiconductors have not been studied thoroughly for their full potential in visible (Vis) to near infrared (NIR) optoelectronic applications. In this dissertation research, we have successfully developed unique synthetic strategies to produce Ge1-xSnx alloy quantum dots (QDs) and tin phosphide (Sn3P4, SnP, and Sn4P3) nanoparticles with tunable physical properties and crystal structures for potential applications in IR technologies. Low-cost, less-non-toxic, and abundantly-produced Ge1-xSnx alloys are an interesting class of narrow energy-gap semiconductors that received noteworthy interest in optical technologies. Admixing of α-Sn into Ge results in an indirect-to-direct bandgap crossover significantly improving light absorption and emission relative to indirect-gap Ge. However, the narrow energy-gaps reported for bulk Ge1-xSnx alloys have become a major impediment for their widespread application in optoelectronics. Herein, we report the first colloidal synthesis of Ge1-xSnx alloy quantum dots (QDs) with narrow size dispersity (3.3±0.5 – 5.9±0.8 nm), wide range of Sn compositions (0–20.6%), and composition-tunable energy-gaps and near infrared (IR) photoluminescence (PL). The structural analysis of alloy QDs indicates linear expansion of cubic Ge lattice with increasing Sn, suggesting the formation of strain-free nanoalloys. The successful incorporation of α-Sn into crystalline Ge has been confirmed by electron microscopy, which suggests the homogeneous solid solution behavior of QDs. The quantum confinement effects have resulted in energy gaps that are significantly blue-shifted from bulk Ge for Ge1-xSnx alloy QDs with composition-tunable absorption onsets (1.72–0.84 eV for x=1.5–20.6%) and PL peaks (1.62–1.31 eV for x=1.5–5.6%). Time-resolved PL (TRPL) spectroscopy revealed microsecond and nanosecond timescale decays at 15 K and 295 K, respectively owing to radiative recombination of dark and bright excitons as well as the interplay of surface traps and core electronic states. Realization of low-to-non-toxic and silicon-compatible Ge1-xSnx QDs with composition-tunable near IR PL allows the unprecedented expansion of direct-gap Group IV semiconductors to a wide range of biomedical and advanced technological studies. Tin phosphides are a class of materials that received noteworthy interest in photocatalysis, charge storage and thermoelectric devices. Dual stable oxidation states of tin (Sn2+ and Sn4+) enable tin phosphides to exhibit different stoichiometries and crystal phases. However, the synthesis of such nanostructures with control over morphology and crystal structure has proven a challenging task. Herein, we report the first colloidal synthesis of size, shape, and phase controlled, narrowly disperse rhombohedral Sn4P3, hexagonal SnP, and amorphous tin phosphide nanoparticles (NPs) displaying tunable morphologies and size dependent physical properties. The control over NP morphology and crystal phase was achieved by tuning the nucleation/growth temperature, molar ratio of Sn/P, and incorporation of additional coordinating solvents (alkylphosphines). The absorption spectra of smaller NPs exhibit size-dependent blue shifts in energy gaps (0.88–1.38 eV) compared to the theoretical value of bulk Sn3P4 (0.83 eV), consistent with quantum confinement effects. The amorphous NPs adopt rhombohedral Sn4P3 and hexagonal SnP crystal structures at 180 and 250 °C, respectively. Structural and surface analysis indicates consistent bond energies for phosphorus across different crystal phases, whereas the rhombohedral Sn4P3 NPs demonstrate Sn oxidation states distinctive from those of the hexagonal and amorphous NPs owing to complex chemical structure. All phases exhibit N(1s) and ʋ(N-H) energies suggestive of alkylamine surface functionalization and are devoid of tetragonal Sn impurities.

In this thesis, geometry is used as a basis for conducting experiments aimed at growing and arranging inorganic minerals on curved interfaces. Mineralisation is directed using crystalline and liquid-crystalline metallic soaps and surfactant/water systems as templates.¶ A review of the history, syntheses, structure and liquid crystallinity of metallic soaps and other amphiphiles is presented as a foundation to understanding the interfacial architectures in mesostructured template systems in general.¶ In this study, a range of metallic soaps of varying chain length and cation type are synthesised and characterised to find potentially useful templates for mineral growth. These include alkaline-earth, transition metal, heavy metal and lanthanide soaps. These are systematically characterised using a variety of analytical techniques, including chemical analyses, x-ray diffraction (XRD) infrared spectroscopy (IR) and differential scanning calorimetry (DSC). Their molecular and crystal structures are studied using transmission electron microscopy (TEM), cryo-TEM, electron diffraction (ED), electron paramagnetic spin resonance (EPR), absorption spectroscopy (UV-VIS), high resolution laser spectroscopy, atomic force microscopy (AFM), nuclear magnetic resonance spectroscopy, scanning electron microscopy (SEM), electron dispersive x-ray analysis (EDXA), thermal gravimetric analysis (TGA) and magnetic measurements. Models for the molecular and crystal structures of metallic soaps are proposed. The soaps are predominantly lamellar crystalline or liquid crystalline lamellar rotor phases with tilted and/or untilted molecular constituents. These display evidence of varying degrees of headgroup organisation, including superstructuring and polymerisation. A single crystal structure is presented for a complex of pyridine with cobalt soap. Simple models for their structure are discussed in terms of their swelling properties in water and oils. Experiments are also presented to demonstrate the sorbent properties of aluminium soaps on oil spills.¶ The thermotropic liquid crystallinity of alkaline earth, transition metal, heavy metal and lanthanide soaps is investigated in detail. This is done to assess their suitability as templates, and to document their novel thermotropic behaviour, particularly the relatively unknown lanthanide soaps. Liquid crystalline behaviours are studied using high-temperature XRD (HTXRD), hot-stage optical microscopy and DSC. Models for a liquid crystalline phase progression from crystals to anisotropic liquids are discussed in terms of theories of self-assembly and interfacial curvature. The terminology required for this is drawn from various nomenclature systems for amphiphilic crystals and liquid crystals. General agreement with previous studies is reported for known soaps, while liquid crystallinity is demonstrated in the lanthanide and some non-lanthanide soaps for the first time. A general phase progression of crystalline lamellar through liquid crystalline lamellar to non-lamellar liquid crystalline is discussed in terms of models concerned with the molecular and crystal structures of the soaps and their phase transitions via headgroup and chain re-arrangements.¶ Experiments aimed at guiding growth of metal sulfides using metallic soaps as templates are described, and a model for this growth is discussed. Metal sulfides have been successfully grown by reacting crystalline and liquid crystalline transition metal and heavy metal soaps with H2S gas at room temperature and at elevated temperature. These have been characterised using XRD, TEM, ED and IR. Sulfide growth is demonstrated to be restricted and guided by the reacting soap template architecture. Zinc, cadmium, indium and lead soaps formed confined nanoparticles within the matrix of their reacting soap template. In contrast, curved and flat sheet-like structures, some resembling sponges were found in the products of sulfided iron, cobalt, nickel, copper, tin and bismuth soaps. A model to explain this behaviour is developed in terms of the crystal and liquid crystal structures of the soaps and the crystal structures of the metal sulfide particles.¶ Liquid crystalline iron soaps have been subjected to controlled thermal degradation yielding magnetic iron oxide nanoparticles. Some XRD and TEM evidence has been found for formation of magnetic mesostructures in heat-treated iron soaps. Models for the molecular and liquid crystalline structure of iron soaps, their thermotropic phase progression and eventual conversion to these magnetic products are discussed. Systematic syntheses of mesoporous silicates from sheeted clays are discussed.¶The templates that have been used are cationic surfactants and small, organic molecular salts. Experiments are reported where a cooperative self-assembly of surfactant/water/kanemite plus or minus salt and oils yields 'folded sheet materials' (FSM'S). Templating of kanemite has also been achieved using cobalt cage surfactants. A theoretical prediction of the specific surface areas and specific volumes of homologous sets of FSM's gave excellent agreement with measured values. The geometry and topology of the mesostructures are discussed. A theoretical model is also discussed regarding the curvature found in the sheets of natural clays , and results of templating clays and silica using metallic soaps are presented. Experiments and a model for low temperature nucleation and growth of microporous silicalite-1 are described in terms of silica templating by water clathrates.¶ Finally, the problem of finding minimal surface descriptions of crystal networks is addressed. Combinatoric methods are used to disprove the existence of possible embeddings of type I and II clathrate networks in non-self intersecting periodic minimal surfaces. The crystal network of the clathrate silicate, melanophlogite is successfully embedded in the WI-10 self-intersecting surface. Details of a previously unreported, genus-25 periodic surface with symmetry Im3m are discussed.

Research on salts species formed by evaporation of aqueous solution of Na2 in the early 1930s. The thermodynamic, crystallographic and many other physical and chemical properties of most of the species formed from this solution has been known for decades. However, there was no complete information or reliable data to confirm the existence of a unique double salt that is rich in sodium carbonate, up until five years ago when a research identified the double salt (~2Na ₂ CO ₃ • Na ₂ SO ₄) from the ternary system Na₂CO ₃Na₂SO ₄ H₂O. Crystallization of this double salt so called sodium sulfate dicarbonate (~2Na ₂ CO ₃ • Na ₂ SO ₄) is known to be a primary contributor to fouling heat transfer equipment in spent-liquor concentrators used in the pulp and paper industry. Therefore, understanding the conditions leading to formation of this double salt is crucial to the elimination or reduction of an industrial scaling problem. In this work, double salts were generated in a batch crystallizer at close to industrial process conditions. X-ray diffraction, calorimetry, and microscopic observation were used to investigate the stability of the salts to in-process aging, isolation and storage, and exposure to high temperature. The results show that care must be taken during sampling on evaporative crystallization. Two apparent crystal habits were detected in the formation of sodium sulfate dicarbonate; the favored habit may be determined by calcium ion impurities in the system. The results also verify that sodium sulfate dicarbonate exists as a unique phase in this system and that remains stable at process conditions of 115-200℃

In this thesis, quantum cluster methods are used to calculate electronic properties of correlated-electron systems. A special focus lies in the determination of the ground state properties of a 3/4 filled triangular lattice within the one-band Hubbard model. At this filling, the electronic density of states exhibits a so-called van Hove singularity and the Fermi surface becomes perfectly nested, causing an instability towards a variety of spin-density-wave (SDW) and superconducting states. While chiral d+id-wave superconductivity has been proposed as the ground state in the weak coupling limit, the situation towards strong interactions is unclear. Additionally, quantum cluster methods are used here to investigate the interplay of Coulomb interactions and symmetry-breaking mechanisms within the nematic phase of iron-pnictide superconductors. The transition from a tetragonal to an orthorhombic phase is accompanied by a significant change in electronic properties, while long-range magnetic order is not established yet. The driving force of this transition may not only be phonons but also magnetic or orbital fluctuations. The signatures of these scenarios are studied with quantum cluster methods to identify the most important effects. Here, cluster perturbation theory (CPT) and its variational extention, the variational cluster approach (VCA) are used to treat the respective systems on a level beyond mean-field theory. Short-range correlations are incorporated numerically exactly by exact diagonalization (ED). In the VCA, long-range interactions are included by variational optimization of a fictitious symmetry-breaking field based on a self-energy functional approach. Due to limitations of ED, cluster sizes are limited to a small number of degrees of freedom. For the 3/4 filled triangular lattice, the VCA is performed for different cluster symmetries. A strong symmetry dependence and finite-size effects make a comparison of the results from different clusters difficult. The ground state in the weak-coupling limit is superconducting with chiral d+id-wave symmetry, in accordance to previous renormalization group approaches. In the regime of strong interactions SDW states are preferred over superconductivity and a collinaer SDW state with nonuniform spin moments on a quadrupled unit cell has the lowest grand potential. At strong coupling, inclusion of short-range quantum fluctuations turns out to favor this collinear state over the chiral phase predicted by mean-field theory. At intermediate interactions, no robust conclusion can be drawn from the results. Symmetry-breaking mechanisms within the nematic phase of the iron-pnictides are studied using a three-band model for the iron planes on a 4-site cluster. CPT allows a local breaking of the symmetry within the cluster without imposing long-range magnetic order. This is a crucial step beyond mean-field approaches to the magnetically ordered state, where such a nematic phase cannot easily be investigated. Three mechanisms are included to break the fourfold lattice symmetry down to a twofold symmetry. The effects of anisotropic magnetic couplings are compared to an orbital ordering field and anisotropic hoppings. All three mechanisms lead to similar features in the spectral density. Since the anisotropy of the hopping parameters has to be very large to obtain similar results as observed in ARPES, a phonon-driven transition is unlikely.

La recherche a pour objet la structuration du champ lexical des mots « chance », « fortune », « hasard » et « risque » du XVIIIe au XXIe siècle. Témoin de mutations qu’a connues la civilisation occidentale durant cette période, ce champ, qui se rattache à la notion de fortune / hasard, présente une relative homogénéité sémantique.Les mots (et leurs dérivés) sont étudiés à travers le déploiement, la régulation et la répartition des normes d’usages, non seulement en français hexagonal, mais aussi en français québécois. L’étude se fonde sur l’exploitation de deux types de corpus. D’une part, un corpus d’articles extraits d’une cinquantaine de dictionnaires sert à mettre en évidence la productivité morphosémantique et sémantique de ces unités dans une perspective historique large. D’autre part, un grand ensemble d’énoncés diversifiés permet, par la mise au jour de types de contextes, d’effectuer un suivi diachronique des usages. L’approche continuiste des différences d’usages s’appuie sur une représentation fréquentielle des changements sémantiques.La thèse apporte une contribution à la question de la variation des usages et du changement sémantique, qui ouvre sur plusieurs perspectives. Elle se veut d’abord une réflexion sur la théorie et la méthodologie descriptives, appréhendées à la lumière de l’analyse de la nature et du rôle des corpus. Elle met ensuite en évidence l’importance de la dimension intersubjective dans l’activité de signification, en particulier le rôle déterminant des structures syntagmatiques dans l’établissement de nouveaux usages sémantiques. Enfin, elle permet de mettre en relation le changement sémantique avec les conditions sociohistoriques et les représentations collectives. / The present study deals with the way in which the lexical field regrouping the words “chance”, “fortune”, “hazard” and “risqué” has been structured in the French language from the eighteenth century till the present day. Revealing major changes in western societies during this period of time, the field, which corresponds to the linguistic representation of the notion of fortune / hasard, presents a certain coherence.We have examined these words and their derived forms through the display, regulation, and distribution of norms of use, not only in Hexagonal French, but also in Quebec French. Two types of corpora have been analysed. On the one hand, a corpus of articles from around 50 dictionaries has been used to emphasize the lexical and semantic productivity of the different units on a large historical scale. On the other hand, in revealing context types, a set of texts reflecting French language varieties has allowed for carrying out a diachronic analysis of lexical uses. The continuist approach to semantic differences rests upon a frequential representation of semantic changes.The thesis brings a significant contribution to the question of usage variations and semantic change, providing new perspectives. It first deals with theory and methodology of lexical description, considered through the analysis of the nature and the role of corpora. It then evidences the central role of syntagmatic structures in the setting of new semantic uses. The study has finally put into relation semantic changes with their historical background and the collective representations of the time.

For medium and high-voltage drive applications, multilevel inverters are very popular. It is due to their superior performance compared to 2-level inverters such as reduced harmonic content in the output voltage and current, lower common mode voltage and dv=dt, and lesser voltage stress on power switches. The popular circuit topologies for multilevel inverters are neutral point clamped, cascaded H-bridge and flying capacitor based circuits. There exist different combinations of these basic topologies to realize multilevel inverters with modularity, better fault tolerance, and reliability. Due to these advantages, multilevel converters are getting good acceptance from the industry, and researchers all over the world are continuously trying to improve the performance of these converters. To meet such demands, three multilevel inverter topologies are proposed in this thesis. These topologies can be used for high-power induction motor drives, and the concepts presented are also applicable for synchronous motor drives, grid-connected inverters, etc. To get nearly sinusoidal phase current waveforms, the switching frequency of the conventional inverter has to be increased. It will lead to higher switching losses and electromagnetic interference. The problem with lower switching frequency is the intro- duction of low order harmonics in phase currents and undesirable torque ripple in the motor. The 5th and 7th harmonics are dominant for hexagonal voltage space-vector based low frequency switching, and it is possible to eliminate these harmonics by dodecagonal switching. Further improvement in the waveform quality is possible by octadecagonal voltage space-vectors. In this case, the complete elimination of 11th and 13th harmonic is possible for the entire modulation range. The concepts of dodecagonal and octadecagonal voltage space-vectors are used in the proposed inverter topologies. The first topology proposed in this thesis consists of cascaded connection of two H-bridge cells. The two cells are fed from unequal DC voltage sources having a ratio of 1 : 0:366, and this inverter can produce six concentric dodecagonal voltage space- vectors. This ratio of voltages can be obtained easily from a combination of star-delta transformers, since 1 : 0:366 = ( p 3 + 1) : 1. The cascaded connection of two H-bridge cells can generate nine asymmetric pole voltage levels, and the combined three-phase inverter can produce 729 voltage space-vectors (9 9 9). From this large number of combinations, only certain voltage space-vectors are selected, which forms dodecagonal pattern. In the case of conventional multilevel inverters, the voltage space-vector diagram consists of equilateral triangles of equal size, but for the proposed inverter, the triangular regions are isosceles and are having different sizes. By properly placing the voltage space-vectors in a sampling period, it is possible to achieve lower switching frequency for the individual cells, with substantial improvement in the harmonic spectrum of the output voltage. During the experimental veri cation, the motor is operated at di erent speeds using open loop v=f control method. The samples taken are always synchronised with the start of the sector to get synchronised PWM. The number of samples per sector is decreased with increase in the fundamental frequency to limit the switching frequency. Even though many topologies are available in literature, the most preferred topology for drives application such as traction drives is the 3-level NPC structure. This implies that the industry is still looking for viable alternatives to construct multilevel inverter topologies based on available power circuits. The second work focuses on the development of a multilevel inverter for variable speed medium-voltage drive application with dodecagonal voltage space-vectors, using lesser number of switches and power sources compared to earlier implementations. It can generate three concentric 12-sided polygonal voltage space-vectors and it is based on commonly available 2-level and 3-level inverters. A simple PWM timing computation method based on the hexagonal space-vector PWM is developed. The sampled values of the three-phase reference voltages are initially converted to the timings of a two-level inverter. These timings are mapped to the dodecagonal timings using a change of basis transformation. The voltage space- vector diagram of the proposed drive consists of sixty isosceles triangular regions, and the dodecagonal timings calculated are converted to the timings of the inner triangles. A searching algorithm is used to identify the triangular region in which the reference vector is located. A front-end recti er that may be easily implemented using standard star-delta transformers is also developed, to provide near-unity power factor. To test the performance of the inverter drive, an open-loop v=f control is used on a three-phase induction motor under no-load condition. The harmonic spectra of the phase voltages were computed in order to analyse the harmonic distortion of the waveforms. The carrier frequency was kept around 1.2 KHz for the entire range of operation. If the switching frequency is decreased, the conventional hexagonal space-vector based switching introduce signifi cant 5th, 7th, 11th and 13th harmonics in the phase currents. Out of these dominant harmonics, the 5th and 7th harmonics can be completely suppressed using dodecagonal voltage space-vector based switching as observed in the first and second work. It is also possible to remove the 11th and the 13th harmonics by using voltage space-vectors with 18 sides. The last topology is based on multilevel octadecagonal (18-sided polygon) voltage space-vectors, and it has better harmonic performance than the previously mentioned topologies. Here, a multilevel inverter system capable of producing three octadecagonal voltage space-vectors is proposed for the fi rst time, along with a simple timing calculation method. The conventional three-level inverters are only required to construct the proposed drive. Four asymmetric power supply voltages with 0:3054Vdc, 0:3473Vdc, 0:2266Vdc and 0:1207Vdc are required for the operation of the drive, and it is the main drawback of the circuit. Generally front-end isolation transformer is essential for high-power drives and these asymmetric voltages can be easily obtained from the multiple windings of the isolation transformer. The total harmonic distortion of the phase current is improved due to the 18-sided voltage space-vector switching. The ratio of the radius of the largest polygon and its inscribing circle is cos10 = 0:985. This ratio in the case of hexagonal voltage space-vector modulation is cos30 = 0:866, which means that the range of the linear modulation for the proposed scheme is signifi cantly higher. The drive is designed for open-end winding induction motors and it has better fault tolerance. It any of the inverter fails, it can be easily bypassed and the drive will be still functional with reduced speed. Open loop v=f control and rotor flux oriented vector control schemes were used during the experimental verifi cation. TMS320F2812 DSP platform was used to execute the control code for the proposed drive schemes. For the entire range of operation, the carrier was synchronized with the fundamental. For the synchronization, the sampling period is varied dynamically so that the number of samples in a triangular region is fi xed, keeping the switching frequency around 1.2 KHz. The average execution time for the v=f code was found to be 20 S, where as for vector control it took nearly 100 S. The PWM terminals and I/O lines of the DSP is used to output the timings and the triangle number respectively. To convert the triangle number and the timings to IGBT gate drive logic, an FPGA (XC3S200) was used. A constant dead-time of 1.5 S is also implemented inside the FPGA. Opto-isolated gate drivers with desaturation protection (M57962L) were used to drive the IGBTs. Hall-effect sensors were used to measure the phase currents and DC bus voltages. An incremental shaft position encoder with 2500 pulse per revolution is also connected to the motor shaft, to measure the angular velocity. 1200 V, 75 A IGBT half-bridge module is used to realize the switches. The concepts were initially simulated and experimentally verifi ed using laboratory prototypes at low power. While these concepts maybe easily extended to higher power levels by using suitably rated devices, the control techniques presented shall still remain applicable.

For medium and high-voltage drive applications, multilevel inverters are very popular. It is due to their superior performance compared to 2-level inverters such as reduced harmonic content in the output voltage and current, lower common mode voltage and dv=dt, and lesser voltage stress on power switches. The popular circuit topologies for multilevel inverters are neutral point clamped, cascaded H-bridge and flying capacitor based circuits. There exist different combinations of these basic topologies to realize multilevel inverters with modularity, better fault tolerance, and reliability. Due to these advantages, multilevel converters are getting good acceptance from the industry, and researchers all over the world are continuously trying to improve the performance of these converters. To meet such demands, three multilevel inverter topologies are proposed in this thesis. These topologies can be used for high-power induction motor drives, and the concepts presented are also applicable for synchronous motor drives, grid-connected inverters, etc. To get nearly sinusoidal phase current waveforms, the switching frequency of the conventional inverter has to be increased. It will lead to higher switching losses and electromagnetic interference. The problem with lower switching frequency is the intro- duction of low order harmonics in phase currents and undesirable torque ripple in the motor. The 5th and 7th harmonics are dominant for hexagonal voltage space-vector based low frequency switching, and it is possible to eliminate these harmonics by dodecagonal switching. Further improvement in the waveform quality is possible by octadecagonal voltage space-vectors. In this case, the complete elimination of 11th and 13th harmonic is possible for the entire modulation range. The concepts of dodecagonal and octadecagonal voltage space-vectors are used in the proposed inverter topologies. The first topology proposed in this thesis consists of cascaded connection of two H-bridge cells. The two cells are fed from unequal DC voltage sources having a ratio of 1 : 0:366, and this inverter can produce six concentric dodecagonal voltage space- vectors. This ratio of voltages can be obtained easily from a combination of star-delta transformers, since 1 : 0:366 = ( p 3 + 1) : 1. The cascaded connection of two H-bridge cells can generate nine asymmetric pole voltage levels, and the combined three-phase inverter can produce 729 voltage space-vectors (9 9 9). From this large number of combinations, only certain voltage space-vectors are selected, which forms dodecagonal pattern. In the case of conventional multilevel inverters, the voltage space-vector diagram consists of equilateral triangles of equal size, but for the proposed inverter, the triangular regions are isosceles and are having different sizes. By properly placing the voltage space-vectors in a sampling period, it is possible to achieve lower switching frequency for the individual cells, with substantial improvement in the harmonic spectrum of the output voltage. During the experimental veri cation, the motor is operated at di erent speeds using open loop v=f control method. The samples taken are always synchronised with the start of the sector to get synchronised PWM. The number of samples per sector is decreased with increase in the fundamental frequency to limit the switching frequency. Even though many topologies are available in literature, the most preferred topology for drives application such as traction drives is the 3-level NPC structure. This implies that the industry is still looking for viable alternatives to construct multilevel inverter topologies based on available power circuits. The second work focuses on the development of a multilevel inverter for variable speed medium-voltage drive application with dodecagonal voltage space-vectors, using lesser number of switches and power sources compared to earlier implementations. It can generate three concentric 12-sided polygonal voltage space-vectors and it is based on commonly available 2-level and 3-level inverters. A simple PWM timing computation method based on the hexagonal space-vector PWM is developed. The sampled values of the three-phase reference voltages are initially converted to the timings of a two-level inverter. These timings are mapped to the dodecagonal timings using a change of basis transformation. The voltage space- vector diagram of the proposed drive consists of sixty isosceles triangular regions, and the dodecagonal timings calculated are converted to the timings of the inner triangles. A searching algorithm is used to identify the triangular region in which the reference vector is located. A front-end recti er that may be easily implemented using standard star-delta transformers is also developed, to provide near-unity power factor. To test the performance of the inverter drive, an open-loop v=f control is used on a three-phase induction motor under no-load condition. The harmonic spectra of the phase voltages were computed in order to analyse the harmonic distortion of the waveforms. The carrier frequency was kept around 1.2 KHz for the entire range of operation. If the switching frequency is decreased, the conventional hexagonal space-vector based switching introduce signifi cant 5th, 7th, 11th and 13th harmonics in the phase currents. Out of these dominant harmonics, the 5th and 7th harmonics can be completely suppressed using dodecagonal voltage space-vector based switching as observed in the first and second work. It is also possible to remove the 11th and the 13th harmonics by using voltage space-vectors with 18 sides. The last topology is based on multilevel octadecagonal (18-sided polygon) voltage space-vectors, and it has better harmonic performance than the previously mentioned topologies. Here, a multilevel inverter system capable of producing three octadecagonal voltage space-vectors is proposed for the fi rst time, along with a simple timing calculation method. The conventional three-level inverters are only required to construct the proposed drive. Four asymmetric power supply voltages with 0:3054Vdc, 0:3473Vdc, 0:2266Vdc and 0:1207Vdc are required for the operation of the drive, and it is the main drawback of the circuit. Generally front-end isolation transformer is essential for high-power drives and these asymmetric voltages can be easily obtained from the multiple windings of the isolation transformer. The total harmonic distortion of the phase current is improved due to the 18-sided voltage space-vector switching. The ratio of the radius of the largest polygon and its inscribing circle is cos10 = 0:985. This ratio in the case of hexagonal voltage space-vector modulation is cos30 = 0:866, which means that the range of the linear modulation for the proposed scheme is signifi cantly higher. The drive is designed for open-end winding induction motors and it has better fault tolerance. It any of the inverter fails, it can be easily bypassed and the drive will be still functional with reduced speed. Open loop v=f control and rotor flux oriented vector control schemes were used during the experimental verifi cation. TMS320F2812 DSP platform was used to execute the control code for the proposed drive schemes. For the entire range of operation, the carrier was synchronized with the fundamental. For the synchronization, the sampling period is varied dynamically so that the number of samples in a triangular region is fi xed, keeping the switching frequency around 1.2 KHz. The average execution time for the v=f code was found to be 20 S, where as for vector control it took nearly 100 S. The PWM terminals and I/O lines of the DSP is used to output the timings and the triangle number respectively. To convert the triangle number and the timings to IGBT gate drive logic, an FPGA (XC3S200) was used. A constant dead-time of 1.5 S is also implemented inside the FPGA. Opto-isolated gate drivers with desaturation protection (M57962L) were used to drive the IGBTs. Hall-effect sensors were used to measure the phase currents and DC bus voltages. An incremental shaft position encoder with 2500 pulse per revolution is also connected to the motor shaft, to measure the angular velocity. 1200 V, 75 A IGBT half-bridge module is used to realize the switches. The concepts were initially simulated and experimentally verifi ed using laboratory prototypes at low power. While these concepts maybe easily extended to higher power levels by using suitably rated devices, the control techniques presented shall still remain applicable.