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The Global ETD Search service is a free service for researchers
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Showing 61 to 70 of 71 (0.111 seconds)Spelling suggestions: "subject:"inn."" "subject:"linn.""
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Oxygen and CO on the Pt3Sn(111) and Pt3Sn(110) surfaces / Sauerstoff und CO auf den Pt3Sn(111) und Pt3Sn(110) OberflächenHoheisel, Martin 15 November 2002 (has links)
The high temperature adsorption of oxygen and the room temperature adsorption of CO on the Pt3Sn(111) and Pt3Sn(110) surfaces have been investigated by scanning tunneling microscopy (STM), low-energy electron diffraction (LEED), and Auger electron spectroscopy (AES). Beforehand the structure of the clean surfaces has been reviewed.
After exposure to several 1000 L O2 at sample temperatures of about 750 K on both Pt3Sn(111) and (110) an ultra-thin Sn-O surface layer is formed. For the (111) X-ray photoelectron spectroscopy (XPS) indicates that this layer does not yet exhibit oxide properties. STM topographs of the Sn-O phase show on both surfaces meshes of highly corrugated protrusions commensurate with the substrate. In the case of the (111), after additional thermal annealing with STM and LEED a (4 × 4) reconstruction is observed, that is due to a (2 × 2) supermesh of depressions in the p(2 × 2) mesh of protrusions. This structure is similar to findings reported for the oxidation of Sn/Pt(111) surface alloys. X-ray photoelectron diffraction (XPD) measurements in comparison with simulations yield a tentative model for the (111) Sn-O layer.
On the Pt3Sn(110) surface after oxygen exposure a c(2 × 2) hexagonal grid of protrusions with regard to the (2 × 1) substrate is observed with STM and LEED. STM reveals the existence of domains due to two equivalent positions of the Sn-O layer relative to the substrate. The domain boundaries zigzag around the [1-10] direction. The Sn-O layer can on both surfaces be removed by thermal annealing to more than 1050 K.
After CO adsorption at room temperature on both Pt3Sn(111) and (110) adsorbate structures are observable with the STM. On the (111) two different types of structures are found: ordered patches of protrusions and unordered clusters. These structures are seen only on (√3 × √3)R30° substrate regions, not on p(2 × 2) regions. Surprisingly on the (110) the CO molecules mostly arrange in dimers. For both (111) and (110) saturation coverage is already reached at about 30% of a closed monolayer. The CO can be desorbed by slightly heating the samples to about 400 K. STM topographs show that on both surfaces CO adsorbes in Pt sites, not on Sn.
It was possible to observe the CO adsorption on the (110) directly live with the STM. The observed adsorption processes hint to a dimer formation mechanism where a preadsorbed monomer and a CO molecule form the gas phase or a precursor phase stick together.
When on partially Sn-O phase covered Pt3Sn(111) and (110) surfaces CO is adsorbed at room temperature, the respective structures coexist. Neither is CO observed on the Sn-O phase nor does a reaction between CO and O occur.
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Synthese intramolekularer Frustrierter Lewis-Paare mit aluminiumbasierten Akzeptoreinheiten und ihre Reaktivität gegenüber kleinen MolekülenFedermann, Patrick 28 February 2023 (has links)
Frustrierte Lewis-Paare (FLPs) bestehen aus einer Lewis-Säure und -Base, die an der gegenseitigen Neutralisierung gehindert werden und so erfolgreich zur Aktivierung kleiner Moleküle eingesetzt werden konnten. Als Elektronenpaarakzeptoren wurden bislang vorwiegend Borane erforscht. Aluminiumbasierte Systeme, insbesondere intramolekularer Art, sind trotz ihrer ausgeprägten Lewis-Acidität unterrepräsentiert. In der vorliegenden Dissertation wurde untersucht, welche Syntheserouten sich zur Darstellung intramolekularer Phosphor/Aluminium-FLPs mit großer räumlicher Trennung der Lewis-Funktionen eignen und welche Reaktivität diese aufweisen. An einem Xanthenrückgrat mit Diphenylphosphineinheit konnten durch Lithiierung und Metathese Dimesityl- und Bis(pentafluorphenyl)alaneinheiten eingeführt werden und die resultierenden P/Al-FLPs sind in der Lage, Tetrahydrofuran zu öffnen. Das perfluorierte Derivat wies dabei eine zehnfach höhere Geschwindigkeitskonstante der Ringöffnungsreaktion auf. Mittels quantenchemischer Rechnungen konnte dies auf die gesteigerte Lewis-Acidität des Aluminiumzentrums zurückgeführt werden. Durch den Zinn-Aluminium-Austausch eines trimethylstannylierten Xanthenvorläufers mit Methylaluminiumverbindungen konnten P/Al-FLPs aufgebaut werden, die durch ein weiteres Äquivalent des Alanpräkursors stabilisiert werden. Die Verbindungen sind imstande, Kohlenstoffdioxid zu aktivieren, wobei die CO2-Addukte der verschiedenen Derivate mit zunehmender Anzahl elektronegativer Substituenten an den Aluminiumzentren eine zunehmende thermodynamische Stabilisierung erfahren. Die neuartige Syntheseroute konnte auch zur Darstellung eines biphenylengebundenen P/Al-FLPs genutzt werden. In diesem Fall ist das Aluminiumzentrum durch die Wechselwirkung mit dem Phosphandonor ausreichend gesättigt, um die Isolierung der gespannten Verbindungen in monomerer Form zu ermöglichen. Dennoch weist das Alan eine hohe Lewis-Acidität auf und der FLP reagiert mit CO2 und Propadien. / Frustrated Lewis pairs (FLPs) consist of a Lewis acid and base, which are prevented from neutralising each other and in turn could be successfully used to activate small molecules. Boranes have been predominantly explored as electron pair acceptors. In contrast, aluminium-based systems, in particular intramolecular ones, are underrepresented despite their pronounced Lewis acidity. The aim of the present dissertation was to fathom which synthetic route is suitable for the preparation of intramolecular phosphorus/aluminium FLPs with large spatial separation of the Lewis functions and to investigate their reactivity. On a xanthene backbone bearing a diphenylphosphine moiety, dimesityl and bis(pentafluorophenyl)alane units could be introduced by lithiation and metathesis, and the resulting P/Al-FLPs are able to open tetrahydrofuran. The perfluorinated derivative exhibited a tenfold higher rate constant of the ring opening reaction. Using quantum chemical calculations, this could be attributed to the increased Lewis acidity of the aluminium centre. Using a tin-aluminum exchange on a trimethylstannylated xanthene precursor with methylaluminium compounds, P/Al-FLPs could be constructed, which are stabilised by another equivalent of the aluminium precursor. The compounds are capable of activating carbon dioxide, and the CO2 adducts of the various derivatives become increasingly stabilised as the number of electronegative substituents at the aluminium centres increases. The novel synthetic route could also be applied for the synthesis of a P/Al-FLP on the biphenylene linker. In this case, the aluminium centre is sufficiently saturated by an interaction with the phosphane donor to permit the isolation of the strained compounds in monomeric form. Nevertheless, the alane exhibits high Lewis acidity and the FLP reacts with CO2 and propadiene.
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Preparation and Reactions of Compounds with Heavier Group 14 Elements in Low Oxidation States / Synthese und Reaktionen von Verbindungen der Schweren Elemente der 14. Gruppe in niedrigen OxidationsstufenSen, Sakya Singha 04 October 2010 (has links)
No description available.
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Design of Phosphorus Centered Janus Head Ligands / Design phosphorzentrierter Januskopf-LigandenObjartel, Ina 31 October 2011 (has links)
No description available.
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Rohstoffprognosen für Zinn, Wolfram, Fluss- und Schwerspat im MittelerzgebirgeBrosig, Andreas, Barth, Andreas, Knobloch, Andreas, Dickmayer, Ellen 04 January 2022 (has links)
Im Rahmen des Projektes ROHSA 3 wurden auf Basis vorhandener und neu verfügbar gemachter Daten Prognosen für Zinn, Wolfram sowie Fluss- und Schwerspat in einem 740 m² großen Gebiet im Mittelerzgebirge angefertigt. Die Karten zeigen höffige Gebieten, wobei für Zinn und Wolfram erstmals auch Mengen-Prognosen erstellt wurden. Geophysikalische, geochemische Daten sowie Lagerstättenindikatoren (z. B. Tektonik, Erz kontrollierende Lithologien) wurden durch die Software advangeo@ aufbereitet und mittels ihrer künstlich neuronalen Netze (KNN) verarbeitet. Durch höhere Datendichte, Einbeziehung dreidimensionaler geologischer Daten und Aufstellung quantitativer Modelle wurde ein deutlicher Erkenntnisfortschritt erzielt.
Redaktionsschluss: 31.07.2020
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Unprecedented Synthetic and Reactivity Studies of Compounds with Low Valent Group 14 ElementsJana, Anukul 22 October 2009 (has links)
No description available.
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Ionenstrahlunterstütztes Wachstum von Zinn-dotierten Indiumoxid-Filmen / Ion beam assisted growth of tin-doped indium oxide filmsThiele, Karola 26 March 2004 (has links)
No description available.
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Skarn testing report: MAP002: D5.4Brosig, Andreas 12 March 2021 (has links)
An assessment of tin-skarn resources in the Erzgebirge, Germany, was conducted with the 3-Part Method. For this purpose a Grade-Tonnage Model for this deposit type was established. A literature review produced grade and tonnage data for 23 skarn deposits, of which 9 are in the assessment area. Based on an existing predictive map created with an AI algorithm, seven permissive tracts with a total area of 776 km² were defined. To estimate the number of undiscovered deposits a panel of five experts in the economic geology of the Erzgebirge was assembled. From the expert estimates and the newly developed Grade-Tonnage Model the undiscovered ore and metal tonnages in each permissive tract were evaluated. In four of the seven tracts the probability of the existence of at least one undiscovered deposit is estimated to be greater than 50%, in permissive tract 2 it is even greater than 90%. In each of these tracts, the median assessed undiscovered ore tonnages are several million tons and the tin resources exceed 10,000 tons. For the most perspective tract (Permissive tract 2) the median estimates are 40.6 Million tons of ore with a tin content of 114,000 tons. For tungsten (tonnages calculated as WO3) the numbers are slightly lower.
The results verify the high resource potential of tin skarns in the Erzgebirge and can be used to guide future exploration activities to the most economically promising permissive tracts.
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Darstellung neuer Organometallhalogenide mit Elementen der 13. und 14. Gruppe des Periodensystems und Versuche zur Synthese von Organogermanolen / Synthesis of novel organometal halides with elements of group 13 and 14 of the periodic system and attempts to prepare organogermanolesHohmeister, Holger 02 July 2003 (has links)
No description available.
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A Novel Approach to Youth Crime Prevention: Mindfulness Meditation Classes in South African Townships / A Novel Approach to Youth Crime Prevention : Mindfulness Meditation Classes in South African TownshipsKneip, Katharina January 2020 (has links)
Children growing up in poor areas with high crime rates are shown to easily get involved in violent actions and criminal gangs. In South Africa, despite considerable efforts to reduce youth delinquency, youth crime rates are still disturbingly high – specifically, in the townships of the Cape Flats. This paper points out an important aspect previously unaddressed by most youth crime prevention: the subconscious roots of youth crime. What if we could develop youth crime prevention programs that manage to impact the subconscious behavioral patterns of youth in high crime areas? This paper proposes a promising and cost-effective approach that has great potential to affect multipe causes of crime: mindfulness meditation. Built upon newest findings in Neuroscience, this paper suggests that mindfulness meditation classes are associated with a reduction in aggressive behavior, a risk factor for youth crime, and an increase in self-efficacy, a protective factor. The impact of mindfulness classes at a high school in Khayelitsha, a poor and violent-stricken township of Cape Town, is analyzed. Self-reported aggression and self-efficacy are measured via a psychometric survey questionnaire created from two well-tested and validated scales. Regression analyses of 384 survey answers provided mixed results. Whilst novice meditators were not associated with higher self-efficacy and lower aggression, long-term meditators performed better in several dimensions of self-efficacy and aggression, yet no significant relationship was found. Further research specifically needs to investigate the moderating effect of age (a proxy for psychological development) on meditation. This study aims to bridge the gap between the outdated paradigms of youth crime prevention and ancient wisdom via ground-breaking new evidence from the field of Neuroscience. This study furthermore hopes to point policy makers toward developing new, integrative and sustainable approaches to youth crime prevention – approaches that give back agency to our youth. / <p>Anders Westholm har inget med betygssättningen att göra annat än i rent formellt hänseende (examinator). Det är han som rapporterar in och skriver under men i sak är det seminarieledaren som har beslutet i sin hand. Statsvetenskapliga institutet har som princip att skilja på handledning och examination vilket innebär att handledaren inte får vara seminarieledare. Seminarieledare och personen som satt betygget var i det här fallet Sven Oskarsson: Sven.Oskarsson@statsvet.uu.se</p>
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